The stability and calibration of water vapor isotope ratio measurements during long-term deployments Public Deposited

http://ir.library.oregonstate.edu/concern/articles/kk91fq63p

To the best of our knowledge, one or more authors of this paper were federal employees when contributing to this work. This discussion paper has been under review for the journal Atmospheric Measurement Techniques (AMT). Please refer to the corresponding final paper in AMT. The published article is copyrighted by the author(s) and published by Copernicus Publications on behalf of the European Geosciences Union. The published article can be found at:  http://www.atmos-meas-tech-discuss.net/8/5425/2015/amtd-8-5425-2015.html

The final revised paper is available at:  http://hdl.handle.net/1957/57875

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  • With the recent advent of commercial laser absorption spectrometers, field studies measuring stable isotope ratios of hydrogen and oxygen in water vapor have proliferated. These pioneering analyses have provided invaluable feedback about best strategies for optimizing instrumental accuracy, yet questions still remain about instrument performance and calibration approaches for multi-year field deployments. With clear scientific potential for using these instruments to carry out long-term monitoring of the hydrological cycle, this study examines the long-term stability of the isotopic biases associated with three cavity-enhanced laser absorption spectrometers – calibrated with different systems and approaches – at two remote field sites: Mauna Loa Observatory, Hawaii, USA, and Greenland Environmental Observatory, Summit, Greenland. The analysis pays particular attention to the stability of measurement dependencies on water vapor concentration and also evaluates whether these so-called concentration-dependences are sensitive to statistical curve-fitting choices or measurement hysteresis. The results suggest evidence of monthly-to-seasonal concentration-dependence variability – which likely stems from low signal-to-noise at the humidity-range extremes – but no long-term directional drift. At Mauna Loa, where the isotopic analyzer is calibrated by injection of liquid water standards into a vaporizer, the largest source of inaccuracy in characterizing the concentration-dependence stems from an insufficient density of calibration points at low humidity. In comparison, at Greenland, the largest source of inaccuracy is measurement hysteresis associated with interactions between the reference vapor, generated by a custom dew point generator (DPG), and the sample tubing. Nevertheless, prediction errors associated with correcting the concentration-dependence are small compared to total measurement uncertainty. At both sites, a dominant source of uncertainty is instrumental precision at low humidity, which cannot be reduced by improving calibration strategies. Challenges in monitoring long-term isotopic drift are also discussed in light of the different calibration systems evaluated.
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  • Bailey, A., Noone, D., Berkelhammer, M., Steen-Larsen, H. C., & Sato, P. (2015). The stability and calibration of water vapor isotope ratio measurements during long-term deployments. Atmospheric Measurement Techniques Discussions, 8, 5425-5466. doi:10.5194/amtd-8-5425-2015
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