A Twist on a Classic Scaffold: Rational Design of a New Bimetallic Platform

Citeable URL: https://ir.library.oregonstate.edu/concern/articles/vd66w8229

Descriptions

Attribute Name	Values
Creator	Rumi, Sultana P. Zakharov, Lev N. Desnoyer, Addison N.
Abstract	Herein, we report the synthesis of a modular family of novel bimetallic tetraamidodiamine (tada) ligands, Li4-R-tada (R = Me3Si, t BuMe2Si, and i Pr3Si). These silylamido ligands display two distinct binding pockets whose steric profiles can be easily tuned by choice of the substituents on silicon We also show that salt metathesis is a convenient route to install these new ligands on the early transition metals titanium(IV) and vanadium(III).
License	All rights reserved
Resource Type	Article
DOI	http://dx.doi.org/10.1039/d4dt01840k
Date Issued	2024-07-31
Journal Title	Dalton Transactions
Academic Affiliation	Chemistry
Rights Statement	In Copyright
Funding Statement (additional comments about funding)	This work was supported by start-up funds from Oregon State University. We acknowledge the support of the Oregon State University NMR Facility funded in part by the National Institutes of Health, HEI Grant 1S10OD018518, and by the M. J. Murdock Charitable Trust grant #2014162. We also acknowledge the M. J. Murdock Charitable Trust (grant SR-2017297) for acquisition of OSU's single crystal diffractometer. We thank Prof. Chong Fang for use of his UV/Vis spectrophotometer.
Publisher	Royal Society of Chemistry
Peer Reviewed	Yes
Language	English [eng]
Funding Body	Oregon State University; Oregon State University NMR Facility - National Institutes of Health; M. J. Murdock Charitable Trust
ISSN	1477-9234