Proline sulphonamide-catalysed Yamada–Otani condensation: reaction development, substrate scope and scaffold reactivity Public Deposited

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  • The development of a proline sulphonamide-catalysed method for enantioselective and diastereoselective construction of functionalized cyclohexenones is described. Impact of catalyst structure as well as solvent effects and additives are explored. A significant substrate scope is demonstrated by variation of both the aldehyde and the enone components. Diastereoselective derivatization of the cyclohexenone scaffold illustrates its utility as a building block for chemical synthesis.
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  • Yang, H., Banerjee, S., & Carter, R. G. (2012). Proline sulphonamide-catalysed yamada-otani condensation: Reaction development, substrate scope and scaffold reactivity. Organic & Biomolecular Chemistry, 10(25), 4851.
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  • description.provenance : Submitted by Deborah Campbell (deborah.campbell@oregonstate.edu) on 2012-08-06T16:17:36Z No. of bitstreams: 1 YangHuaChemistryProlineSulphonamideCatalysed.pdf: 2605013 bytes, checksum: ae3734a605d5eceb1968c5440d9e5ab2 (MD5)
  • description.provenance : Approved for entry into archive by Deborah Campbell(deborah.campbell@oregonstate.edu) on 2012-08-06T16:34:28Z (GMT) No. of bitstreams: 1 YangHuaChemistryProlineSulphonamideCatalysed.pdf: 2605013 bytes, checksum: ae3734a605d5eceb1968c5440d9e5ab2 (MD5)
  • description.provenance : Made available in DSpace on 2012-08-06T16:34:28Z (GMT). No. of bitstreams: 1 YangHuaChemistryProlineSulphonamideCatalysed.pdf: 2605013 bytes, checksum: ae3734a605d5eceb1968c5440d9e5ab2 (MD5) Previous issue date: 2012-07-07

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