Exploratory studies of the mechanism of 1,3 sigmatropic ring expansion reactions Public Deposited

http://ir.library.oregonstate.edu/concern/graduate_thesis_or_dissertations/2227ms406

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  • The potassium salts of certain 1-vinylcycloalk-3-en-l-ols have been found to undergo sigmatropic ring expansion rearrangements in HMPA. Preliminary investigations of several benzo-substituted medium ring systems were undertaken in order to determine which of these was best suited for further study. A synthetic sequence leading to the formation of 5-methy1-6-viny1-7,8,9,10-tetrahydro-6-benzocyclo-octenol, which will be used in a study of the stereochemistry of the 1,3 sigmatropic ring expansion reaction, was carried out.
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  • description.provenance : Approved for entry into archive by Patricia Black(patricia.black@oregonstate.edu) on 2013-09-10T19:29:48Z (GMT) No. of bitstreams: 1 JamesCorinne1981.pdf: 331486 bytes, checksum: 06ad6a2a94f1ae73beb2e9291357e195 (MD5)

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