Lattice effects of lithium hydroxide : isotopic effects and factor group analysis Public Deposited

http://ir.library.oregonstate.edu/concern/graduate_thesis_or_dissertations/3b591c77m

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  • The infrared absorption spectrum from 3200 cm⁻¹ to 4025 cm⁻¹ of thin crystals of ⁶LiOH (99%⁶Li.) is presented and compared to the spectrum of [superscript]NLiOH (93%⁷Li). A shift in only one of the band pairs supports the lattice combinations model and assists in making assignments for the major features of the spectra. Inelastic neutron scattering, far infrared, deuteration and polarization data from other workers were also utilized in making the assignments. An analysis of transitions at critical points for non-zero K as well as K= 0, is presented and includes a discussion of degeneracies that occur at some of these points.
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