Graduate Thesis Or Dissertation

 

A pyrolysis of cis-1-trimethylsiloxy-1-cyclopropyl-3-cyclononene : the thermal isomerization of 2-phenyl-1-trimethylsiloxy-1-vinylcyclononane Public Deposited

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  • Part 1 The pyrolysis of cis-1-trimethylsiloxy-1-cyclopr opyl-3-cyclononene in the temperature range 285-350° is described. Instead of siloxy-Cope rearrangement, undesired desiloxylation took place. Part 2 Gas-phase pyrolytic rearrangement of 2-phenyl-1-trimethylsiloxy-1-vinylcyclononane was investigated in a static system in the temperature range 213-330°. It was discovered that three major products resulted: cis- and tran-4-phenyl-1-trimethylsiloxy-l-cycloundecene and 4-phenyl-undecanone. Although an appreciable amount of polymerization occurred at high temperature, it was not significant at low temperature.
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