Graduate Thesis Or Dissertation
 

Development of an autonomous in-situ instrument for long-term monitoring of Cu(II) in the marine environment

Public Deposited

Downloadable Content

Download PDF
Request Accessible Version
https://ir.library.oregonstate.edu/concern/graduate_thesis_or_dissertations/4j03d373v

Descriptions

Attribute NameValues
Creator
Abstract
  • An autonomous, in-situ instrument was developed to detect dissolved copper in seawater, suitable for deployment on time scales from weeks to months. A commercially available in-situ nitrate analyzer (YSI 9600) was adapted to measure copper (II) in seawater by chemiluminescence. Modifications included construction of a photomultiplier (PMT) based detector and flow-cell, the use of more chemically resistant plastics for parts in contact with the reagents, addition of an in-line acidification step and optimization of the method and flow parameters. Filtration to 0.45μm and acidification online (pH ~1.7) produces a measurement of total dissolved Cu(II). Calibration is achieved by periodically analyzing ligand-stabilized seawater standard and blank solutions stored at pH 8 and acidified online. Micro solenoid pumps take in sample and dispense reagent, standard, and blank solutions, which are stored in 1L plastic bags. All waste is collected in two 5L bags. In-situ, the instrument has an average detection limit of 0.8(3) nM, a sample precision of 7%, and an accuracy, assessed over all deployments, of 17%. The instrument is capable of functioning autonomously for 25 days sampling every hour and calibrating every six hours, with reagent consumption being the limiting factor.
License
Resource Type
Date Available
Date Issued
Degree Level
Degree Name
Degree Field
Degree Grantor
Commencement Year
Advisor
Committee Member
Academic Affiliation
Non-Academic Affiliation
Subject
Rights Statement
Publisher
Peer Reviewed
Language
File Format
File Extent
  • 994177 bytes
Replaces
Accessibility Feature

Relationships

Parents:

This work has no parents.

In Collection:

Items

Thumbnail Title Date Uploaded Visibility Actions
file details Thesis_CEH_12_22.pdf 2017-10-19 Public Download