Decomposition of perfluoroalkyl groups bonded to boron

Graduate Thesis Or Dissertation

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Citeable URL: https://ir.library.oregonstate.edu/concern/graduate_thesis_or_dissertations/4q77ft98v

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Attribute Name	Values
Creator	Walsh, James Elroy William
Abstract	All attempted synthesis of perfluoroalkyl boron bonded groups have resulted in the formation of boron-fluorine bonds from the probable decomposition by α-fluorine transfer. The substance alkali metal di-n- butylborate (I) has been identified as the potassium derivative by its reaction with di-n-butylboron chloride and isolation of potassium chloride. The reaction of potassium di- n- butylborate (I) with trifluoroiodomethane in aprotic solvents was studied by ¹⁹F NMR resulting in the identification of a transient intermediate trifluoromethyldi- n-butylboron which decomposed upon warming.
Resource Type	Masters Thesis
Date Available	2013-10-30T23:21:08+00:00
Date Issued	1976-07-28
Degree Level	Master's
Degree Name	Master of Science (M.S.)
Degree Field	Chemistry
Degree Grantor	Oregon State University
Commencement Year	1977
Advisor	Parsons, Theran D.
Academic Affiliation	Chemistry
Non-Academic Affiliation	Oregon State University. Graduate School
Subject	Chemical bonds
权利声明	Copyright Not Evaluated
Publisher	Oregon State University
Peer Reviewed	No
Language	English [eng]
Digitization Specifications	File scanned at 300 ppi (Monochrome) using Capture Perfect 3.0.82 on a Canon DR-9080C in PDF format. CVista PdfCompressor 4.0 was used for pdf compression and textual OCR.
Replaces	http://hdl.handle.net/1957/43621

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