Graduate Thesis Or Dissertation

 

Catalytic rearrangement of cyclodeca-1,2,5-triene and oxymercuration of bicyclo-[7.1.0]-deca-2,3-diene Público Deposited

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https://ir.library.oregonstate.edu/concern/graduate_thesis_or_dissertations/6969z311n

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  • The reaction of cyclodeca-1,215triene with mercuric salts gave only rearranged hydrocarbon, tricyclo[4.4.0.0²'⁴]deca-5ene in acetic acid. Other catalysts [Rh(CO)₂C1]₂ and AgC10₄ gave the same rearranged hydrocarbon. The isomerization is proposed to proceed through a "metalcomplexed" carbenoid intermediate. The reaction of bicyclo[7.1.0 ]deca-213diene gave oxymercurated products.
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