Formation of alkyl-and dialkylcarbenes. The 3-cyclohexenyl carbinyl carbene system Public Deposited

http://ir.library.oregonstate.edu/concern/graduate_thesis_or_dissertations/8623j098f

Descriptions

Attribute NameValues
Creator
Abstract or Summary
  • The 3-cyclohexenyl carbinyl carbene species was formed by the thermal decomposition of the p-toluenesulfonylhydrazone sodium salt and by oxidation of the hydrazone. Several oxidizing agents were studied. The products were investigated under aprotic and protic conditions and at various temperatures. The diazocompound was formed as an intermediate and found to be relatively stable although extremely sensitive to the conditions. When the diazocompound was decomposed, the azine and the hydrocarbon products, both major and minor, were characterized. Under aprotic conditions the hydrocarbon yield was small and showed a large amount of β-insertion. The β- to γ- insertion ratio decreased as the system became protic. A comparison of the two methods of carbene formation is presented.
Resource Type
Date Available
Date Copyright
Date Issued
Degree Level
Degree Name
Degree Field
Degree Grantor
Commencement Year
Advisor
Academic Affiliation
Non-Academic Affiliation
Subject
Rights Statement
Peer Reviewed
Language
Digitization Specifications
  • File scanned at 300 ppi using Capture Perfect 3.0 on a Canon DR-9050C in PDF format. CVista PdfCompressor 5.0 was used for pdf compression and textual OCR.
Replaces
Additional Information
  • description.provenance : Made available in DSpace on 2014-04-18T16:31:05Z (GMT). No. of bitstreams: 1 CrouseDaleM1967_Redacted.pdf: 1613002 bytes, checksum: 436dcffdc0da24d833f8783b3f87a76c (MD5) Previous issue date: 1966-09-02
  • description.provenance : Approved for entry into archive by Patricia Black(patricia.black@oregonstate.edu) on 2014-04-16T19:17:40Z (GMT) No. of bitstreams: 1 CrouseDaleM1967_Redacted.pdf: 1613002 bytes, checksum: 436dcffdc0da24d833f8783b3f87a76c (MD5)
  • description.provenance : Submitted by Alex McFerrin (amscannerosu@gmail.com) on 2014-04-16T00:36:02Z No. of bitstreams: 1 CrouseDaleM1967_Redacted.pdf: 1613002 bytes, checksum: 436dcffdc0da24d833f8783b3f87a76c (MD5)
  • description.provenance : Approved for entry into archive by Katy Davis(kdscannerosu@gmail.com) on 2014-04-18T16:31:05Z (GMT) No. of bitstreams: 1 CrouseDaleM1967_Redacted.pdf: 1613002 bytes, checksum: 436dcffdc0da24d833f8783b3f87a76c (MD5)

Relationships

In Administrative Set:
Last modified: 08/04/2017

Downloadable Content

Download PDF
Citations:

EndNote | Zotero | Mendeley

Items