Graduate Thesis Or Dissertation
 

The kinetics of the chlorination of copper in the thin film range

Public Deposited

Contenu téléchargeable

Télécharger le fichier PDF
https://ir.library.oregonstate.edu/concern/graduate_thesis_or_dissertations/8s45qd20j

Descriptions

Attribute NameValues
Creator
Abstract
  • The kinetics of the chlorination of copper in the thin film range at room temperature was studied by using a wiped, rotating cylindrical copper cathode which was partially submerged in an electrolyte. Experiments were conducted at three different partial pressures: 1.00, 0.44 and 0.21 atm. of chlorine gas which was saturated with water vapor. The chlorination of copper was found to follow the logarithmic equation NAT= K ₁ In ( K ₂ t + 1.0 ) where W. is the weight of copper chloride formed per unit area during exposure time t. The constant K1 was found to be independent of the chlorine partial pressure while the constant K₂ was proportional to the square root of the chlorine partial pressure for the two pressure ranges 1.00 and 0.44 atm. The most satisfactory interpretation of the experimental data is the mutually-blocking pores mechanism in which the rate determining step is assumed to be the transport of chlorine across the chloride film through pores and paths of loosely arranged atoms.
Resource Type
Date Available
Date Issued
Degree Level
Degree Name
Degree Field
Degree Grantor
Commencement Year
Advisor
Academic Affiliation
Non-Academic Affiliation
Subject
Déclaration de droits
Publisher
Peer Reviewed
Language
Digitization Specifications
  • File scanned at 300 ppi (Monochrome, 24-bit Color) using ScandAll PRO 1.8.1 on a Fi-6670 in PDF format. CVista PdfCompressor 4.0 was used for pdf compression and textual OCR.
Replaces

Des relations

Parents:

This work has no parents.

Dans Collection:

Articles

La vignette Titre Date de téléchargement Visibilité actes
file details HieuLeM1977.pdf 2017-08-17 Public Télécharger