The photochemistry of some O-(methylcarbamoyl) oximes Public Deposited

http://ir.library.oregonstate.edu/concern/graduate_thesis_or_dissertations/9593tz16t

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  • The photochemistry of aldicarb and two related compounds, 0-(methylcarbamoyl) isobutyraldehyde oxime and 0-(methylcarbamoyl) trimethylacetaldehyde oxime was explored under laboratory conditions. Upon irradiation aldicarb decomposed rapidly to methylamine, dimethylamine, tetramethylsuccinonitrile, and 1-methylthio-2, 3-dicyano-2, 3-dimethylbutane. The other two compounds decomposed only after a long period of irradiation. The difference in reactivity was attributed to a photodesmotic interaction between the sulfur and the imine double bond in aldicarb.
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  • File scanned at 300 ppi (Monochrome) using ScandAll PRO 1.8.1 on a Fi-6670 in PDF format. CVista PdfCompressor 4.0 was used for pdf compression and textual OCR.
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  • description.provenance : Approved for entry into archive by Patricia Black(patricia.black@oregonstate.edu) on 2013-10-07T15:51:37Z (GMT) No. of bitstreams: 1 McCarthyKermitC1979.pdf: 503835 bytes, checksum: 4817a6fea404ed84ec9cf6250331e784 (MD5)
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