- The El Salvador porphyry copper deposit in the Indio Muerto district of northern Chile has been geologically investigated for more than 60 years and provides one of the best bases for understanding similar environments of ore formation elsewhere in the world. Fourteen new zircon U/Pb isotopic ages obtained via in situ SHRIMP-RG analysis are here coupled with previous geological studies to allow refinement of the timing of Eocene porphyry magma emplacement responsible for copper and molybdenum mineralization that occurs in several ore bodies within the district. The earliest intrusions are rhyolites that crop out throughout the district, but are more abundant in the north. In contrast, the later granodiorite porphyries were emplaced only in the central and southern parts of the district. Two age periods of mineralization have been documented using zircon U/Pb geochronology. The low grade and small copper deposit at Old Camp in the northern district is associated with a quartz porphyry intrusion that yielded an age of 43.6 ± 0.5 Ma, whereas the main copper molybdenum deposit at Turquoise Gulch is associated with emplacement of the granodioritic L porphyry plug that yielded an age of 42.0 ± 0.5 Ma. The final intrusion is a series of latite porphyry dikes, which post-date ores and yielded a U/Pb zircon age of 41.6 ± 0.5 Ma. Inherited Eocene zircons with ages from ~45 Ma to ~47 Ma are found within younger porphyry intrusions and likely formed via magmatic recycling of older intrusions. Therefore, the zircon U/Pb ages suggest magmatism spanned approximately 5 million years from 47 to 42 Ma, with hydrothermal copper-molybdenum ores dominantly forming during the final stages of porphyry emplacement.
Geochemical analyses by XRF, ICP-MS, electron microprobe and laser-ablation ICP-MS define a wide range of major, minor and trace element contents for the Eocene porphyry intrusions within the district. The early rhyolite and quartz porphyry intrusions have rare earth contents with strong negative europium anomalies and relatively low Sr/Y and Sm/Yb ratios consistent formation via fractional crystallization of plagioclase-rich mineral assemblages from more mafic parental melts. The granodiorite porphyries have no europium anomalies and a wide range of Sr/Y and Sm/Yb ratios that support an origin via fractional crystallization of garnet, hornblende ± titanite, and minor plagioclase from an andesitic parental melt. The granodiorite intrusions at M Gulch – Copper Hill are ~1 m.y. older than and have less evolved trace element ratios than the younger granodiorite intrusions associated with the main mineralization event. The evolving Eocene intrusions are the result of lower to middle crust melts ascending to mix with silica-rich differentiated melts derived from fractional crystallization of older andesitic magmas. Progressive decrease of Eu/Eu* ratios in the zircons with decreasing age gives direct evidence in support of the hypothesis that the main ore mineralization is directly related to the evolution of the upper crustal magma reservoir to progressively more oxidized conditions.
A second goal of this study was to document the mineralogy and zonation of altered wall rock at Lassen National Volcanic Park in northern California, in order to understand the pressure, temperature, fluid composition, and epithermal processes along the southern flank of Lassen Peak. Extensive epithermal wall rock alteration occurs along the southern flank of the Cascadia volcano and includes both active and fossil geothermal systems. Geologic mapping coupled with mineral identification using a portable infrared spectrometer and X-ray diffraction outline several hydrothermal systems within the park. Currently active, steam-heated acid sulfate alteration is characterized by kaolinite, alunite, opal, and cristobalite with accessory iron sulfates. The active hydrothermal zones are proximal to thermal pools and fumaroles at Sulphur Works, Pilot Pinnacle, Little Hot Springs Valley, and Bumpass Hell. At least three fossil systems occur within andesite lavas and flow breccias of the eroded Pleistocene Brokeoff Volcano. Intermediate argillic alteration occurs at higher elevations on the flanks of the eroded volcano and is characterized by mixed layer illite-smectite, quartz, pyrite, and albite. Propylitic alteration occurs within the eroded lower elevations of Little Hot Springs Valley and is characterized by chlorite, calcite, quartz, pyrite, illite, albite, and rare epidote. Also present to a lesser extent is an advanced argillic alteration defined by pyrophyllite, dickite, alunite, kaolinite, and quartz formed at Pilot Pinnacle.