Equilibria in the ion exchange systems H⁺¹-CS⁺¹, H⁺²-Sr⁺², H⁺¹-Ce⁺³, Cs⁺¹-Sr⁺², Sr⁺²-Ce⁺³, H⁺¹-Cs⁺¹-Sr⁺², H⁺¹-Cs⁺¹-Ce⁺³ and H⁺¹-Sr⁺²-Ce⁺³ Public Deposited

http://ir.library.oregonstate.edu/concern/graduate_thesis_or_dissertations/nv935730r

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  • A new method for determining ion exchange equilibrium data by liquid scintillation counting of the equilibrated solution phase is described. This method has been applied to determine equilibria between Dowex 50W X8, a commercial strong cation exchange resin, and binary and ternary solution containing the varying combinations of H⁺¹, Cs⁺¹, Sr⁺² and Ce⁺³. Equilibrium isotherms at room temperature are presented for total solution normalities of 0.1, 0.5 and 1.5, 2.5 or 3.0 normal. These data are correlated and examined in terms of phase, chemical and Donnan equilibrium theories. Finally the feasibility of determining ternary equilibrium data from binary data is examined.
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  • File scanned at 300 ppi using ScandAll PRO 1.8.1 on a Fi-6770A in PDF format. CVista PdfCompressor 4.0 was used for pdf compression and textual OCR.
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