Progress Towards the Total Synthesis of Bazzanin K Public Deposited

http://ir.library.oregonstate.edu/concern/graduate_thesis_or_dissertations/p5547v242

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  • Molecular chirality plays a critical role in chemistry, biology, and medicine. To study and better understand conformational chirality, it is necessary to obtain structurally interesting molecules that exhibit this form of chirality. Our lab utilizes total synthesis and methodological development to obtain conformationally chiral natural products of interest. We believe that bazzanin K is a chiral molecule although it lacks sp³ hybridized stereocenters. To test this hypothesis, we set out to synthesize bazzanin K, separate the potential enantiomers, and measure the energy barrier of racemization. The progress towards the total synthesis of bazzanin K is described herein.
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  • description.provenance : Approved for entry into archive by Julie Kurtz(julie.kurtz@oregonstate.edu) on 2015-07-22T18:54:38Z (GMT) No. of bitstreams: 1 SalvoPatrickJ2015.pdf: 6217537 bytes, checksum: beabe8cf441d8c92f839ebd870bb213c (MD5)
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