Application of the least squares criterion to the determination of molecular compliance constants Public Deposited

http://ir.library.oregonstate.edu/concern/graduate_thesis_or_dissertations/pr76f565v

Descriptions

Attribute NameValues
Creator
Abstract or Summary
  • The development of a least squares model for the determination of compliance constants from various combinations of vibration frequency, mean square amplitudes of vibration and centrifugal distortion data is discussed. The resultant model is applied to frequency and mean square amplitude data for NO₂ and N₂O₄ and to frequency and centrifugal distortion data for SO₂ . For NO₂ and SO₂ it was possible to use various combinations of data and weight matrices so that some statements could be made regarding the utility of the model. A recently developed theory concerning the anharmonicity effect due to the presence of the low frequency torsion made in X₂Y₄ type molecules was applied to N₂O₄ giving results which point to a plausible explanation for some of the unusual bands observed for this type molecule.
Resource Type
Date Available
Date Copyright
Date Issued
Degree Level
Degree Name
Degree Field
Degree Grantor
Commencement Year
Advisor
Academic Affiliation
Non-Academic Affiliation
Subject
Rights Statement
Peer Reviewed
Language
Digitization Specifications
  • File scanned at 300 ppi using ScandAll PRO 1.8.1 on a Fi-6670 in PDF format. CVista PdfCompressor 5.0 was used for pdf compression and textual OCR.
Replaces
Additional Information
  • description.provenance : Made available in DSpace on 2014-04-28T22:49:19Z (GMT). No. of bitstreams: 1 OttingerRobertS1966.pdf: 30694189 bytes, checksum: f36f8aaa83fa7fe1a2244bfb5cba8a89 (MD5) Previous issue date: 1965-07-13
  • description.provenance : Approved for entry into archive by Katy Davis(kdscannerosu@gmail.com) on 2014-04-28T22:49:19Z (GMT) No. of bitstreams: 1 OttingerRobertS1966.pdf: 30694189 bytes, checksum: f36f8aaa83fa7fe1a2244bfb5cba8a89 (MD5)
  • description.provenance : Submitted by Lauren Kaysen (lkscannerosu@gmail.com) on 2014-04-24T22:50:01Z No. of bitstreams: 1 OttingerRobertS1966.pdf: 30694189 bytes, checksum: f36f8aaa83fa7fe1a2244bfb5cba8a89 (MD5)
  • description.provenance : Approved for entry into archive by Patricia Black(patricia.black@oregonstate.edu) on 2014-04-25T14:04:25Z (GMT) No. of bitstreams: 1 OttingerRobertS1966.pdf: 30694189 bytes, checksum: f36f8aaa83fa7fe1a2244bfb5cba8a89 (MD5)

Relationships

Parents:

This work has no parents.

Last modified

Downloadable Content

Download PDF

Items