The siloxy-cope rearrangement of 1,2-divinyl-1-trimethyl-siloxycyclohexane and related systems. The acid-catalyzed rearrangement of bicyclo [5.1.0] octyl-8-methanol

Graduate Thesis Or Dissertation

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Citeable URL: https://ir.library.oregonstate.edu/concern/graduate_thesis_or_dissertations/r207ts275

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Attribute Name	Values
Creator	Walton, Edward Samuel
Abstract	Part I The pyrolysis of cis- and trans- 1, 2-divinyl-1- trimethylsiloxy - cyclohexane, II- and III-TMS, under the same conditions as the pyrolysis of cis-l-vinyl -1-trimethylsiloxycyclooct-3-ene, I-TMS, confirms that a sequence of concerted reactions for the rearrangement of II- and III-TMS to trans-l-trimethylsiloxycyclodec-3-ene, IV-TMS, is a viable pathway in the overall rearrangement of I -TMS, Part II The solvolysis of exo-bicyclo [5.1.0] octyl -8- methanol in aqueous dioxane with perchloric acid catalysis leads to a 4:1 ratio of bicyclo [5. 2. 0] nonan-8-ol and 2-vinylcycloheptanol.
Resource Type	Masters Thesis
Fecha Disponible	2014-01-27T18:38:26+00:00
Fecha de Emisión	1973-03-16
Degree Level	Master's
Degree Name	Master of Science (M.S.)
Degree Field	Chemistry
Degree Grantor	Oregon State University
Commencement Year	1973
Advisor	Thies, Richard W.
Academic Affiliation	Chemistry
Non-Academic Affiliation	Oregon State University. Graduate School
Subject	Oxo compounds
Declaración de derechos	Copyright Not Evaluated
Publisher	Oregon State University
Peer Reviewed	No
Language	English [eng]
Digitization Specifications	File scanned at 300 ppi (Monochrome) using Capture Perfect 3.0 on a Canon DR-9050C in PDF format. CVista PdfCompressor 4.0 was used for pdf compression and textual OCR.
Replaces	http://hdl.handle.net/1957/45310

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