Graduate Thesis Or Dissertation

 

Symmetry allowed charge-transfer transitions between spin-orbit states in the gaseous dihalides of Mn, Co, Ni, and Cu Público Deposited

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https://ir.library.oregonstate.edu/concern/graduate_thesis_or_dissertations/t722hd33d

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  • The spin-orbit states of both the ground and several charge-transfer-excited electronic configurations of gaseous MnX₂, CoX₂, NiX₂, and CuX₂ are derived. Only one-electron transitions from the ground electronic state are considered. The molecules are treated as linear in both the ground and excited states. In each case, the spin-orbit states of the excited configurations are components of zero-order terms with the same multiplicity as the ground state zero-order term. The symmetry allowed, electric dipole excited, spin-orbit states are found for each molecule. Polarization properties of transitions to these states are also considered. The transitions expected for each gaseous molecule and the information obtained from symmetry and polarization studies are discussed.
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  • File scanned at 300 ppi using ScandAll PRO 1.8.1 on a Fi-6770A in PDF format. CVista PdfCompressor 5.0 was used for pdf compression and textual OCR.
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