Article
 

Sorption and transformation of the reactive tracers resazurin and resorufin in natural river sediments

Public Deposited

Downloadable Content

Download PDF
https://ir.library.oregonstate.edu/concern/articles/4m90dx47v

Descriptions

Attribute NameValues
Creator
Abstract
  • Resazurin (Raz) and its reaction product resorufin (Rru) have increasingly been used as reactive tracers to quantify metabolic activity and hyporheic exchange in streams. Previous work has indicated that these compounds undergo sorption in stream sediments. We present laboratory experiments on Raz and Rru transport, sorption, and transformation, consisting of 4 column and 72 batch tests using 2 sediments with different physicochemical properties under neutral (pH=7) and alkaline (pH=9) conditions. The study aimed at identifying the key processes of reactive transport of Raz and Rru in streambed sediments and the experimental setup best suited for their determination. Data from column experiments were simulated by a travel-time-based model accounting for physical transport, equilibrium and kinetic sorption, and three first-order reactions. We derived the travel-time distributions directly from the breakthrough curve (BTC) of the conservative tracer, fluorescein, rather than from fitting an advective-dispersive transport model, and inferred from those distributions the transfer functions of Raz and Rru, which provided conclusive approximations of the measured BTCs. The most likely reactive transport parameters and their uncertainty were determined by a Markov chain–Monte Carlo approach. Sorption isotherms of both compounds were obtained from batch experiments. We found that kinetic sorption dominates sorption of both Raz and Rru, with characteristic timescales of sorption in the order of 12 to 298 min. Linear sorption models for both Raz and Rru appeared adequate for concentrations that are typically applied in field tracer tests. The proposed two-site sorption model helps to interpret transient tracer tests using the Raz–Rru system.
  • This is the publisher’s final pdf. The published article is copyrighted by the author(s) and published by Copernicus Publications on behalf of the European Geosciences Union. The published article can be found at: http://www.hydrology-and-earth-system-sciences.net/home.html.
Resource Type
DOI
Date Available
Date Issued
Citation
  • Lemke, D., González-Pinzón, R., Liao, Z., Wöhling, T., Osenbrück, K., Haggerty, R., & Cirpka, O. A. (2014). Sorption and transformation of the reactive tracers resazurin and resorufin in natural river sediments. Hydrology and Earth System Sciences, 18(8), 3151-3163. doi:10.5194/hess-18-3151-2014
Journal Title
Journal Volume
  • 18
Journal Issue/Number
  • 8
Rights Statement
Funding Statement (additional comments about funding)
  • This work was supported by grants fromthe Ministry of Science, Research and Arts of Baden-Württemberg(AZ Zu 33-721.3-2), the Helmholtz Centre for EnvironmentalResearch, Leipzig (UFZ), the German Academic ExchangeService (DAAD), and the US National Science Foundation, grant#EAR 08-38338.
Publisher
Peer Reviewed
Language
Replaces

Relationships

Parents:

This work has no parents.

Items

Thumbnail Title Date Uploaded Visibility Actions
file details HaggertyRoyCEOASSorptionTransformationReactive.pdf 07/26/2017 Public
file details HaggertyRoyCEOASSorptionTransformationReactive_SupplementaryMaterial.xlsx 07/26/2017 Public
file details HaggertyRoyCEOASSorptionTransformationReactive_SupplementCoverLetter.pdf 07/26/2017 Public