Index Catalog // ScholarsArchive@OSU

A kinetic investigation of the mechanism and intermediates of the chromium(VI)-Iodide reaction

Creator:: Gaswick, Dennis Charles
Resource Type:: Dissertation
Full Text:: A kinetic investigation of the mechanism and

A study of the iodine-formate reaction in dimethylsulfoxide-water mixtures

Creator:: Hiller, Frederick Wayne
Resource Type:: Dissertation
Full Text:: A study of the iodine-formate reaction in

Characterization of a trivalent-nitrogen center. Nucleophilic substitution on hydroxylamine-o-sulfonic acid in dimethyl sulfoxide-water solvents

Creator:: Sudbury, Barry Arnold
Resource Type:: Dissertation
Full Text:: : CHARACTERIZATION OF A TRIVALENT-NITROGEN CENTER. NUCLEOPHILIC SUBSTITUTION ON HYDROXYLAMINE-0- SULFONIC ACID IN

Reactions and stereochemistry of thiolato and sulfenato cobalt (III) complexes

Creator:: Herting, Daniel L.
Abstract:: This thesis describes a study of the synthesis, stereochemistry, and reactivity of cobalt(III) cysteinato (CyS) and related thiolato complexes. The preparation of [Co(en)₂CyS]⁺ resulted in a product solution containing a mixture of diastereomers in the ratio 2.3:1 (Δ:A). The isomers were separated by ion exchange chromatography, and their absolute configurations...
Resource Type:: Dissertation
Full Text:: -penicillamine disulfide) from Aldrich Chemical Co. The pH of solutions was measured with a Broadly James Ag

Synthesis and oxidation of metal-thiolate compounds which mimic the active site function of thiolate dioxygenase enzymes

Creator:: Schussel, Leonard J.
Abstract:: Part I describes the synthesis of bis(fac-S)((tris)2-aminoethanethiolatoiron( III))iron(III) chloride. The compound was first discovered during an attempt to prepare a ternary complex of iron, thiolate and pi-acid ligand. The compound is a reasonably air-stable iron(III)-thiolate that contains a linear tri-iron cluster with each iron bridged to the adjacent iron by...
Resource Type:: Dissertation
Full Text:: Department for everlasting support as a teaching assistant. Also much thanks to Dr. James H. Krueger for

The kinetics of the reaction between peroxydisulfate and iodide ions in dimethyl sulfoxide

Creator:: Burns, Bruce
Resource Type:: Masters Thesis
Full Text:: ) is that it has.a two term rate law, viz: Rate = dl3 /dt = ka S2O8 ì+ kb[I i i S2O82-I. A

[Lambda hyperon]-((R)-cysteinesulfenamido-N,S) bis (ethylenediamine) cobalt(III) complex : Characterization of the complex and kinetics and mechanism of formation and base-catalyzed decomposition

Creator:: Sanguanruang, Oravan
Resource Type:: Dissertation
Full Text:: Broadley James Ag/AgC1 micro combination electrode and a Chemtrix type 60A digital pH meter. Reagent-grade

Synthesis and oxidation of cysteine- and penicillamine- containing Fe(III) and Co(III) complexes. Analogs for the active metal sites of the cysteine and cysteamine dioxygenases

Creator:: Miller, Krys J.
Abstract:: The first part of this thesis describes a study of the characteristics of oxidation of a 1:2 iron(III):thiolate system in methanolic solution and in water. This system was investigated as a potential analog for the cysteine- and cysteamine-dioxygenase catalyzed 0₂-oxidation of cysteine and cysteamine, respectively, to the corresponding sulfinic acids....
Resource Type:: Dissertation
Full Text:: . The pH of solutions was measured with a Broadley James Ag/AgC1 microcombination electrode and a

Nuclear magnetic resonance investigation of acidic proton behavior in phenylsulfonylacetone and acetohydroxamic acid

Creator:: Stanclift, William Everett
Resource Type:: Masters Thesis
Full Text:: Acetohydroxarnic Acid Abstract approved The cornpound phenylsulfonylacetone was prepared, using a method

Kinetics and mechanisms of nucleophilic displacement reactions with S-methyl-S-phenyl-sulfiminium perchlorate

Creator:: KiYokane, Richard Junji
Resource Type:: Masters Thesis
Full Text:: in the S-methyl- S-phenylsulfiminium perchlorate is a medium-soft acid center on the Pearson HSAB

ScholarsArchive@OSU

A kinetic investigation of the mechanism and intermediates of the chromium(VI)-Iodide reaction

A study of the iodine-formate reaction in dimethylsulfoxide-water mixtures

Characterization of a trivalent-nitrogen center. Nucleophilic substitution on hydroxylamine-o-sulfonic acid in dimethyl sulfoxide-water solvents

Reactions and stereochemistry of thiolato and sulfenato cobalt (III) complexes

Synthesis and oxidation of metal-thiolate compounds which mimic the active site function of thiolate dioxygenase enzymes

The kinetics of the reaction between peroxydisulfate and iodide ions in dimethyl sulfoxide

[Lambda hyperon]-((R)-cysteinesulfenamido-N,S) bis (ethylenediamine) cobalt(III) complex : Characterization of the complex and kinetics and mechanism of formation and base-catalyzed decomposition

Synthesis and oxidation of cysteine- and penicillamine- containing Fe(III) and Co(III) complexes. Analogs for the active metal sites of the cysteine and cysteamine dioxygenases

Nuclear magnetic resonance investigation of acidic proton behavior in phenylsulfonylacetone and acetohydroxamic acid

Kinetics and mechanisms of nucleophilic displacement reactions with S-methyl-S-phenyl-sulfiminium perchlorate

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