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Filtering by: Alternative title ssim Special report 433 Academic Affiliation Chemistry Creator Blake, T. A.

High-resolution infrared studies of perdeutero-spiropentane, C₅D₈

Creator:

Erickson, Blake Alexander, Ju, X., Nibler, Joesph W., Beaudry, C. M., and Blake, T. A.

Abstract:

Perdeutero-spiropentane (C₅D₈) has been synthesized and infrared and Raman spectra are reported for the first time. Wavenumber assignments are made for most of the fundamental vibrational modes. Gas phase infrared spectra were recorded at a resolution (0.002 cm⁻¹) sufficient to resolve individual rovibrational lines and show evidence of strong Coriolis...

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would be reported in a subsequent paper, however we have been unable to find any such published report
Coriolis analysis of several high-resolution infrared bands of bicyclo[111]pentane-d₀ and -d₁

Creator:

Perry, A., Martin, M. A., Nibler, J. W., Maki, A., Weber, A., and Blake, T. A.

Abstract:

High-resolution infrared absorption spectra have been analyzed for two bicyclo[111]pentane isotopologues, C₅H₈ (-d₀) and C₅H₇D (-d₁), where in the latter the D-atom replaces a hydrogen on the C₃ symmetry axis such that the molecular symmetry is reduced from D₃ₕ to C₃ᵥ. Two (a"₂) parallel bands, v₁₇ and v₁₈, of bicyclopentane-d₀...

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we report two fits. Fit 1 was made with w1,1 set at the theoretical value, 0.228 cm�1, and Fit 2 was