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Donor centers in vanadium pentoxide

Creator:: Yerke, John Fredric
Abstract:: The dielectric relaxation of V₂ 0₅ was investigated using the method of Davidson and Cole. By means of an Argand diagram, deviation from an exact Debye dielectric was established. This was done with the parameter β. For a Debye dielectric β= 1. The largest value of β for V₂O₅ was...
Resource Type:: Masters Thesis
Full Text:: PENTOXIDE Abstract approved: Redacted for Privacy A.B. Scott The dielectric relaxation of V 2 0 5 was

Substituent effects in hydrogen abstraction by trichloromethyl radical from 10-substituted-9-methylanthracenes : a linear free energy study

Creator:: Nolan, Gary Scott
Resource Type:: Masters Thesis
Full Text:: THESIS OF GARY SCOTT NOLAN for the degree of MASTER OF SCIENCE in CHEMISTRY presented on e IP t cv-vi

Partial chemical speciation techniques for aquatic humic-metal complexes

Creator:: Chase, Duane Scott
Resource Type:: Masters Thesis
Full Text:: -metal complexes AN ABSTRACT OF THE THESIS OF Duane Scott Chase for the degree of Master of Science

Thermodynamics of the reaction between F and M centers in KBr

Creator:: Li, Tsai-chi
Resource Type:: Masters Thesis
Full Text:: CENTERS IN KBr Abstract approved: Redacted for Privacy Allen B. Scott The thermal equilibrium between F

The effect of oxide impurity on the conductivity of potassium chloride

Creator:: Kouts, Daberath
Abstract:: Direct current conductivity measurements on KC1:O[superscript]= crystals were used to determine an enthalpy of 0.42 ev for the dissociation for anion-vacancy-oxide ion complex. The entropy of dissociation was found to be approximately -4x 10⁻⁴ev deg⁻¹. The intrinsic "activation" energy was found to be 1.91 ev as compared to 1.95 ev,...
Resource Type:: Masters Thesis
Full Text:: rvr PnT A cqTTTAir ('T-TT TTW, Redacted for Privacy Abstract approved: Allen B. Scott Direct current

The reaction between O-ions and F centers

Creator:: Staible, Thomas Fredrick
Abstract:: The photochemical reaction between O⁻ ions and F centers was investigated. The activation energy was determined by the Arrhenius law to be 0.10 + 0.04 eV for temperature below 180°K. The diffusion of alpha centers towards the oxide ion was eliminated as the rate limiting step and the low trapping...
Resource Type:: Masters Thesis
Full Text:: : Redacted for privacy Dr. Allen B. Scott The photochemical reaction between 0 ions and F centers was

Carbene chemistry : I. Stereochemical integrity at Cα in ketone tosylhydrazones : II. Hydrogen migration in 2-carbena-6, 6-dimethylnorbornane

Creator:: Balyeat, John Robert
Abstract:: The tosylhydrazones of exo-3-deuteriocamphor and 2- deuterio-2,4-dimethy1-3-pentanone were treated with Nbromosuccinimide (NBS) and pyruvic acid to regenerate the parent ketones. The ketones from the pyruvic acid cleavage show a significant loss of deuterium. The ketones from the NBS cleavage show no loss of deuterium, indicating that stereochemical integrity at. C[subscript...
Resource Type:: Masters Thesis
Full Text:: C: PROGRAMS FOR THE HEWLETT-PACKARD 55 CALCULATOR TO HANDLE THE COMPUTATION OF %D

Electrochemical studies of liquid chlorocuprates(I)

Creator:: Silkey, James R.
Abstract:: This research emphasized fundamental physical and electrochemical studies of systems based on the room temperature fused salt, triethyl-ammonium dichlorocuprate(I). Such systems, which must be maintained under a protective atmosphere, were also used in some preliminary battery studies. Spectra of dark green solutions of copper (II) chloride in triethylammonium dichlorocuprate(I) obey...
Resource Type:: Masters Thesis
Full Text:: ) obey Beer's law, with an absorption maximum at 402 nm, c 2.02x10 3 lit /mot cm. This behavior is

The conductivity of lead oxide doped potassium chloride single crystals

Creator:: Knepp, Donald Jack
Abstract:: A comparison was made of the d.c. conductivity of KCI:Pb²⁺ and KCl:PbO single crystals at temperatures greater than 325°C. The energy of activation was 0.72 ev for all crystals. Lead concentration was determined by chemical, optical and electrical methods. The half band width of the UV absorption band at 273...
Resource Type:: Masters Thesis
Full Text:: . William J. Fredericks A comparison was made of the d. c. conductivity of KCI:Pb 2+ and KC1:PbO single

Tertiary amine complexes of cobalt (II) and nickel (II) trifluoromethanesulfonates

Creator:: Jansky, Michael Thelen
Abstract:: Hydrated cobalt(II) and nickel(II) trifluoromethanesulfonates have been prepared by a previously reported procedure, and have been characterized for the first time as [ Co(H₂O)₆] (CF₃SO₃)₂H₂O and [Ni(H₂O)₆] (CF₃SO₃)₂. These formulations are based on analyses, near-infrared spectra, and on measurements of the ligand field electronic spectra and the magnetic susceptibilities. The...
Resource Type:: Masters Thesis
Full Text:: (II) and Nickel(II) Trifluoromethane - sulfonate Hydrates 22 Cobalt(II) m-Bromobenzoate 22 C obalt

ScholarsArchive@OSU

Donor centers in vanadium pentoxide

Substituent effects in hydrogen abstraction by trichloromethyl radical from 10-substituted-9-methylanthracenes : a linear free energy study

Partial chemical speciation techniques for aquatic humic-metal complexes

Thermodynamics of the reaction between F and M centers in KBr

The effect of oxide impurity on the conductivity of potassium chloride

The reaction between O-ions and F centers

Carbene chemistry : I. Stereochemical integrity at Cα in ketone tosylhydrazones : II. Hydrogen migration in 2-carbena-6, 6-dimethylnorbornane

Electrochemical studies of liquid chlorocuprates(I)

The conductivity of lead oxide doped potassium chloride single crystals

Tertiary amine complexes of cobalt (II) and nickel (II) trifluoromethanesulfonates

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