Index Catalog // ScholarsArchive@OSU

A pyrolysis of cis-1-trimethylsiloxy-1-cyclopropyl-3-cyclononene : the thermal isomerization of 2-phenyl-1-trimethylsiloxy-1-vinylcyclononane

Creator:: Choi, Young Bok
Abstract:: Part 1 The pyrolysis of cis-1-trimethylsiloxy-1-cyclopr opyl-3-cyclononene in the temperature range 285-350° is described. Instead of siloxy-Cope rearrangement, undesired desiloxylation took place. Part 2 Gas-phase pyrolytic rearrangement of 2-phenyl-1-trimethylsiloxy-1-vinylcyclononane was investigated in a static system in the temperature range 213-330°. It was discovered that three major products resulted: cis- and...
Resource Type:: Masters Thesis
Full Text:: Redacted for privacy Dr. Richard W. Thies The pyrolysis of cis -1 tr imethyls iloxy- 1 - cyclopr opyl- 3

Dipole relaxation effects in doped potassium chloride by the double crystal method

Creator:: Chaney, Robert Edgar
Abstract:: The investigation of impurity effects on the properties of alkali halide crystals has often been difficult because of the variation of procedures used in various experiments. The purpose of this work is to develop a self consistent method of measuring the IV dipole polarization properties of single crystals while eliminating...
Resource Type:: Dissertation
Full Text:: privacy C/W. J. Fredericks The investigation of impurity effects on the properties of alkali halide

Oxy-Cope, and Siloxy-Cope rearrangement of cis-1-vinylcyclooct-3-en-1-ol

Creator:: Chin, Alice Wai-lee
Abstract:: Both oxy-Cope and siloxy-Cope rearrangements involve (1, 3) and (3, 3) sigrnatropic shifts. Both the concerted mechanism, and the stepwise mechanism via a diradical intermediate are possible. In a cyclic system such as cis-l-vinylcyclooct-3-en-l-ol, the thermal rearrangement takes place preferably through a diradical intermediate. At high temperature, the reaction also...
Resource Type:: Masters Thesis
Full Text:: Rearrangement of cis-l-vinyl- cyclooc t-3 -en -I .ol, Abstract approved: Redacted for Privacy Dr. Richard W

The siloxy-cope rearrangement of 1,2-divinyl-1-trimethyl-siloxycyclohexane and related systems. The acid-catalyzed rearrangement of bicyclo [5.1.0] octyl-8-methanol

Creator:: Walton, Edward Samuel
Abstract:: Part I The pyrolysis of cis- and trans- 1, 2-divinyl-1- trimethylsiloxy - cyclohexane, II- and III-TMS, under the same conditions as the pyrolysis of cis-l-vinyl -1-trimethylsiloxycyclooct-3-ene, I-TMS, confirms that a sequence of concerted reactions for the rearrangement of II- and III-TMS to trans-l-trimethylsiloxycyclodec-3-ene, IV-TMS, is a viable pathway in the...
Resource Type:: Masters Thesis
Full Text:: approved: Part I Redacted for Privacy Dr. Richard W. Thies The pyrolysis of cis- and trans- 1, 2-divinyl

The photodecomposition of t-butyl bicyclo [7.1.0] decane-2-percarboxylate

Creator:: McRitchie, Donna Louise
Abstract:: This paper describes the synthesis of t-butyl bicyclo[7.1.0] decane-2-percarboxylate and its photolytic decomposition. The title compound was found to undergo simple homolytic cleavage when exposed to light of 2537 A; producing the cyclodecyl radical, carbon dioxide, and t-butoxy radical. The largest percentage of products arose from an intimate radical pair...
Resource Type:: Masters Thesis
Full Text:: Abstract approved: Redacted for Privacy Richard W. Thies This paper describes the synthesis of t-butyl

A mechanism for filiform corrosion of aluminum

Creator:: Hoover, Steven Edward
Abstract:: A mechanism for filiform corrosion of aluminum is proposed based on experimental evidence and the known aqueous chemistry of the trivalent aluminum ion. Experimental methods utilized include autoradiographs with Cl³⁶; pH paper determination of the filiform head pH; activator concentration and activation period as they affect filiform growth. The pH...
Resource Type:: Masters Thesis
Full Text:: /) / / Title: A MECHANISM FOR FILIFORM CORROSION OF ALUMINUM Abstract approved Redacted for privacy Dr. W. H

An investigation of the molecular structure and vibrational potential function of thiazyl chloride (NSCl) by electron diffraction and infrared spectroscopy

Creator:: Emken, Walter Charles
Resource Type:: Dissertation
Full Text:: Abstract approved Redacted for privacy IK6nneth W, edberg The molecular structure of thiazyl chloride has

Oxymercuration of cyclodeca-1,2,5,8-tetraene

Creator:: Hong, Pak-Kong
Abstract:: The reactions of cyclodeca-1, 2, 5, 8-tetraene with mercuric salts in solvents of varying nucleophilicity are described. Instead of forming the usual oxymercuration products reported for reactions of olefins and allenes with mercuric salts, the major products obtained in the present cases result from the initial electrophilic addition of the...
Resource Type:: Masters Thesis
Full Text:: CYCLODECA-1, 2, 5, 8-TETRAENE Abstract approved: Redacted for privacy Dr. Richard W. Thies The reactions

Spectroscopic studies of matrix isolated high temperature molecules

Creator:: Lesiecki, Michael Louis
Resource Type:: Dissertation
Full Text:: Stratton for Michael Louis Lesiecki A CKNOWLEDGEMENT I would like to thank Dr. Joseph W. Nib ler for

Infrared spectra and geometry of matrix isolated rare-earth and IIIB metal fluorides

Creator:: Wesley, Robert Dee
Abstract:: The infrared absorption spectra (40-800 cm⁻¹) of the trifluorides of Sc, Y, La, Ce, Pr, Nd, Sm, Eu, Tb, Ho, Er, Tm, and Yb isolated in solid argon, krypton and nitrogen matrices have been obtained. For PrF₃ the symmetric and asymmetric stretching modes were observed; PrF₃ is accordingly assigned a...
Resource Type:: Dissertation
Full Text:: Dr. C. W. DeKock The infrared absorption spectra (40-800 cm-1) of the trifluorides of Sc, Y, La, Ce

ScholarsArchive@OSU

A pyrolysis of cis-1-trimethylsiloxy-1-cyclopropyl-3-cyclononene : the thermal isomerization of 2-phenyl-1-trimethylsiloxy-1-vinylcyclononane

Dipole relaxation effects in doped potassium chloride by the double crystal method

Oxy-Cope, and Siloxy-Cope rearrangement of cis-1-vinylcyclooct-3-en-1-ol

The siloxy-cope rearrangement of 1,2-divinyl-1-trimethyl-siloxycyclohexane and related systems. The acid-catalyzed rearrangement of bicyclo [5.1.0] octyl-8-methanol

The photodecomposition of t-butyl bicyclo [7.1.0] decane-2-percarboxylate

A mechanism for filiform corrosion of aluminum

An investigation of the molecular structure and vibrational potential function of thiazyl chloride (NSCl) by electron diffraction and infrared spectroscopy

Oxymercuration of cyclodeca-1,2,5,8-tetraene

Spectroscopic studies of matrix isolated high temperature molecules

Infrared spectra and geometry of matrix isolated rare-earth and IIIB metal fluorides

Limit your search

Academic Affiliation

Advisor

Commencement Year

Creator

Date

Decade

Degree Field

Degree Level

Degree Name

Language

Non-Academic Affiliation

Peer Reviewed

Resource Type

Rights Statement

Subject

Search Constraints

Search Results

Limit your search