The need for field and laboratory studies of the physical and
chemical behavior of environmentally significant organic molecules often
poses problems because of the toxicity of the chemical and the difficulty
of detecting it at environmentally significant concentrations.
Two dysprosium tracers, dysprosium (III) trisacetylacetonate trihydrate
and dysprosium(III) trisdibenzoylmethane monohydrate, were...
The design and construction of two new sample injection systems or nozzles, for use with the Oregon State electron diffraction apparatus are discussed. One of these nozzles was intended for use with volatile samples the vapors of which were to be heated or cooled over the range -196 to 540°C;...
The potassium salts of certain 1-vinylcycloalk-3-en-l-ols have
been found to undergo sigmatropic ring expansion rearrangements in
HMPA. Preliminary investigations of several benzo-substituted medium
ring systems were undertaken in order to determine which of these
was best suited for further study. A synthetic sequence leading to
the formation of 5-methy1-6-viny1-7,8,9,10-tetrahydro-6-benzocyclo-octenol,
which...
We have investigated the gaseous structure of cyclohexane-
1,4-dione via electron diffraction. The large amplitude
motion, as suggested from spectroscopic, dipole moment
and earlier electron diffraction data was studied. The
structure was refined in two types of models: a single
"distorted boat" conformer, and a model comprised of a
superposition...
The study of the obstructive factor by Hawkes (11) showed a relation
between the obstructive factor and velocity using a continuous
method. Later, Bowers and Hawkes (12) developed a similar method with
some improvements in the apparatus and found out that the obstructive
factor was not flow dependent. This study...
The atmospheric trace element abundances associated with slash
burning have been measured by instrumental neutron activation analysis
(INAA). On site ground level samples were collected during the slash
burning season using high volume samplers and a cascade impactor. In
addition to the air samples, soil, wood and ashed wood samples...
I. Lithium alkyl and aryl monosubstituted cyclooctatetraenide
dianions (Li₂ C₈H₇-R; R = methyl, n- butyl, sec- butyl, tert- butyl,
phenyl and benzyl) were synthesized by the reaction of the appropriate
organolithium reagent with cyclooctatetraene in diethyl ether or
tetrahydrofuran. The reaction occurred cleanly and with good yield
of lithium monosubstituted...