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Filtering by: Creator Hill, David Ray Remove constraint Creator: Hill, David Ray Academic Affiliation Chemistry Remove constraint Academic Affiliation: Chemistry Decade 2000-2009 Remove constraint Decade: 2000-2009

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  • Studies on nitrogen containing secondary metabolites from terrestrial and marine origin

    Creator:
    Barrios Sosa, Ana Carolina
    Abstract:
    PART I. A deuterium exchange analysis of 2,5-dihydroxyacetanilide (5) in the absence and presence of DHAE II was performed to test the nucleophilicity of the substrate in the absence and presence of catalyst. In addition, inhibition studies using 1,4-dihydroxybenzene were performed to determine the role that the N-acetyl side chain...
    Resource Type:
    Dissertation
    Full Text:
    Abstract approved: David A. Home Kevin P. Gable PART I. A deutenum exchange analysis of 2,5

  • Synthesis of furanoeremophilane sesquiterpenoids

    Creator:
    Shanmugham, Meenakshi Sundaram
    Abstract:
    Two approaches to the tricyclic core of the furanoeremophilane sesquiterpenoids are described. The first approach entails a projected Diels-Alder/retro Diels-Alder reaction of an acetylenic oxazole 64. Construction of the pivotal aldehyde 67 commenced from ketone 68. The acetyenic moiety was then introduced via a Felkin-Ahn addition of lithiopropyne to aldehyde...
    Resource Type:
    Dissertation
    Full Text:
    Gable, Professor David Home and Professor Max Deinzer for their time and support. I thank the past and

  • Part I: Synthetic studies toward the southern portion of Azaspiracid-1; Part II: Total synthesis of amphidinolide B₁ and the proposed structure of amphidinolide B₂

    Creator:
    Lu, Liang
    Abstract:
    The structural architecture present in marine toxin azaspiracid - 20 stereocenters, 9 rings, 3 separated spirocenters - has attracted considerable synthetic attention. Our efforts toward the synthesis of azaspiracid have led to the completion of both C₁-C₂₆ northern and C₂₇-C₄₀ southern halves. Herein, the synthesis of southern FGHI ring system...
    Resource Type:
    Dissertation
    Full Text:
    . Wei Kong and Prof. David Cann for their helpful advice and help. Additionally, I would like to

  • Galvanostatic control of ion selective electrodes with the solvent polymeric membrane

    Creator:
    Perera, Hasini R.
    Abstract:
    Detection technique that proposed utilizing electrochemically controlled, reversible ion extraction into polymeric membrane in an alternating galvanostatic/ potentiostatic mode was introduced. This method is studied in detail to comprehend the advantages of the novel sensor (pulstrode) compared to the potentiometric ion selective electrode (ISE), studies included possible applications and limitations....
    Resource Type:
    Dissertation
    Full Text:
    . David Hakleman and Dr. John Westall. During my stay at OSU, I was fortunate to work with an excellent

  • Fabrication and application of polymer based microfluidic devices

    Creator:
    Koesdjojo, Myra T.
    Abstract:
    The concept of reducing laboratory operations in scale such that they fit on a microfluidic chip has been met with great enthusiasm. Lab-on-a-chip devices promise to be cost effective to operate due to reduced reagent consumption, have the potential to offer shorter analysis times due to their short path lengths,...
    Resource Type:
    Dissertation
    Full Text:
    to Dr. Chih-hung Chang, Dr. Claudia Maier, Dr. David Hackleman, and Dr. Michael Penner, for their

  • Synthesis and structure of new transition metal containing bismuth oxides

    Creator:
    Xun, Xiumei
    Abstract:
    Exploratory synthesis is the discovery of new compounds with interesting structures and properties. The subject of this thesis is exploratory synthesis of bismuth containing oxides. Bismuth containing oxides have many interesting properties, which are ionic conductivity, ferromagnetism, superconductivity, ferroelectricity, ferroelasticity and catalytic. These properties are closely related to their specific...
    Resource Type:
    Dissertation
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    cation) have been synthesized. The structures were refined by powder X-ray and neutron diffraction data

  • Synthesis and study of transparent p- and n-type semiconductors and luminescent materials

    Creator:
    Park, Cheol-Hee
    Abstract:
    New transparent p- and n-type semiconductors and luminescent materials have been prepared and characterized. Synthesis, structures, optical and electrical properties of new chalcogenide fluoride p-type transparent semiconductors MCuQF (M=Ba, Sr; Q=S, Se, Te) are described. Band-gap tuning and improvement in conductivity through p-type doping are demonstrated in the family. The...
    Resource Type:
    Dissertation
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    properties of new potential X-ray phosphors Lu2O2S:Ln3 (Ln=Eu, Tb) are summarized. ©Copyright by Cheol

  • High quantum-yield phosphors via quantum splitting and upconversion

    Creator:
    Jeong, Joayoung
    Abstract:
    The Gd3+ ion has been used to induce quantum splitting in luminescent materials by using cross-relaxation energy transfer (CRET). In Nd:LiGdF4, quantum splitting results from a two-step CRET between Gd3+ and Nd3+, first involving a transition 6G→6I on Gd3+ and an excitation within the 4f3 configuration of Nd3+ followed by...
    Resource Type:
    Dissertation
    Full Text:
    material GdZrF7 were grown, and its structure was established via single-crystal X-ray diffraction

  • Theory of negative thermal expansion

    Creator:
    Tao, Ju Zhou
    Abstract:
    Two framework oxide materials of the MO₃ network type have been synthesized and structurally characterized by synchrotron and X-ray powder diffraction and the Rietveld method in the temperature range 25~500 K. The results show one of them to be a low thermal expansion material. Theoretical studies of negative thermal expansion...
    Resource Type:
    Dissertation
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    synthesized and structurally characterized by synchrotron and X-ray powder diffraction and the Rietveld

  • Asymmetric synthesis of cyclopropanes via a "zipper reaction"

    Creator:
    Lincoln, Christopher M.
    Abstract:
    The rearrangement of a homoallyl cation to a cyclopropylcarbinyl cation is thought to play a role in the biogenesis of a variety of cyclopropane-containing natural products,¹ a hypothesis which has previously led to the design of successful biomimetic syntheses of several natural products.² The strategy underlying this approach to cyclopropane...
    Resource Type:
    Dissertation
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    through derivatization and the absolute stereochemistry was verified by X-ray crystallography. Redacted