Index Catalog // ScholarsArchive@OSU

Prediction and Measurement of Polycyclic Aromatic Hydrocarbons (PAHs) Transformation Products in the Environment.

Creator:: Titaley, Ivan A.
Abstract:: Polycyclic aromatic hydrocarbons (PAHs) are a group of environmental contaminants consisting of fused benzene rings. Parent-PAHs, methylated-PAHs (MPAHs), and PAHs with molecular weight of 302 a.m.u (MW302-PAHs) are considered as unsubstituted-PAHs. These unsubstituted-PAHs undergo transformation reactions resulting in the formation of PAH-transformation products (PAH-TPs), or substituted-PAHs, including nitrated-, oxygenated-, and...
Resource Type:: Dissertation
Full Text:: : _____________________________________________________________________ Staci L. Massey Simonich Polycyclic aromatic hydrocarbons (PAHs) are a group of

Investigation of Chain Extension Approaches for the Stereoselective Reagent-Controlled Synthesis of alpha-Heteroatom Substituted Alkyl Boronic Esters

Creator:: Barsamian, Adam L.
Abstract:: Two distinct strategies were explored for the enantioselective synthesis of α-heteroatom substituted alkyl boronic esters by stereoselective reagent-controlled homologation using transient chiral carbenoid reagents CHYMX (Y = heteroatom, X = nucleofuge, M = electrofuge). In the first case, a stereospecific reagent-controlled homologation (sStReCH) approach to α-alkoxyalkylboronates using α-metalated S,O- and...
Resource Type:: Dissertation
Full Text:: AN ABSTRACT OF THE DISSERTATION OF Adam L. Barsamian for the degree of Doctor of Philosophy in

Development of novel analytical methods to detect emerging contaminants in aqueous environmental matrices using large-volume injection

Creator:: Backe, Will J.
Abstract:: It is the responsibility of humans, as environmental stewards, to monitor our impact on the environment so that efforts can be made to remediate the effects of our actions and change behaviors. To better understand our environmental footprint, sensitive and simple analytical methods are needed to quantify the contaminants that...
Resource Type:: Dissertation
Full Text:: .; Wilson, V. S.; Gray, L. E.; Ankley, G. T., Environ Health Perspect 2005, 114, (S-1). (19) Barnes, K

Conformationally chiral diphenylethers and the enantioselective Ullmann etherification

Creator:: Salih, M. Quamar
Abstract:: Since the discovery of molecular chirality in 1848, this notion has had a substantial impact on medicine, biology, and chemistry. Extensive effort has been directed towards the construction of chiral molecules that contain sp³ hybridized stereogenic centers. In contrast, less effort has been dedicated to molecules that are chiral by...
Resource Type:: Dissertation
Full Text:: ! stereochemistry.!Acerogenins!L!and!C!are!achiral!compounds.! ! The! remaining!DAEHs!members,!which!are! the

Towards the Perfect Marriage Between Theory and Experiments in Drug Discovery and Synthesis : Insights into Structure Determination of Complex Natural Products and Mechanistic Understandings of Lactam Synthesis

Creator:: Snyder, Kevin M.
Abstract:: In this report, three studies are presented that aid in the development of drug discovery and their synthesis. In each, the importance of the marriage between computations and experiments is highlighted. Continued efforts in this vein are essential for future efforts towards improving human health. The first case study investigated...
Resource Type:: Masters Thesis
Full Text:: ] residues are inverted from L to D, was consistent with the spectra of the authentic natural product. In

C–H···O Non-Classical Hydrogen Bonding in the Stereomechanics of Organic Transformations: Theory and Recognition

Creator:: Johnston, Ryne C. and Cheong, Paul Ha-Yeon
Abstract:: This manuscript describes the role of non-classical hydrogen bonds (NCHBs), specifically C–H···O interactions, in modern synthetic organic transformations. Our goal is to point out the seminal examples where C–H···O interactions have been invoked as a key stereocontrolling element and to provide predictive value in recognizing future and/or potential C–H···O interactions...
Resource Type:: Article
Full Text:: . Am. Chem. Soc., 1920, 42, 1419–1433. 2 (a) L. Pauling, The nature of the chemical bond and the

Enigmatic Quantum Materials: Novel Spin-Orbit Coupled 4d/5d Metal Oxides and Intermetallics

Creator:: Wallace, Maxwell K.
Resource Type:: Dissertation
Full Text:: synthesis. S.L. Kumari and M.K. Wallace collected electronic properties and J.T. Barnes and B. Tong

Metal-oxo Clusters as Novel Photolithographic Materials: How Understanding the Chemistry of HafSOx Informs Next-Generation Patterning Systems

Creator:: Amador, Jenn M.
Abstract:: The solution chemistry and kinetic behavior of hafnium peroxy sulfate solutions ("HafSOx") is described in terms of peroxide content and solution speciation. Additionally, thin film behavior, including thermal behavior and solubility, is characterized, and a mechanism of patterning is presented, as well as parameters that should be considered when looking...
Resource Type:: Dissertation
Full Text:: -Albrecht, T.; Russell, T. P.; Rotello, V. M. Nature, 2000, 404, 746-748. [4] Long, D.-L.; Burkholder

Iron and copper chalcogenides : photovoltaic absorber candidates and YZrF7 : a new upconversion host, Iron and copper chalcogenides : photovoltaic absorber candidates and YZrF₇ : a new upconversion host

Creator:: Jieratum, Vorranutch
Abstract:: The materials Fe₂(Si,Ge)(S,Se)₄, Cu₃PS[subscript 4-x]Se[subscript x] (0 ≤ x ≤ 4), and Cu₃PxAs[subscript 1-x]S₄ (0 ≤ x ≤ 1) have been synthesized and studied as new earth-abundant absorbers for single and multijunction photovoltaic cells as well as solar fuel generation. The synthesis, single-crystal growth, and optical and electrical properties of...
Resource Type:: Dissertation
Full Text:: . [4] Gray, J. L. In Handbook of Photovoltaic Science and Engineering; Luque, A.; Hegedus, S.; 2 nd

Magnetic particles for selective extraction of trace analytes in microfluidic devices

Creator:: Tennico, Yolanda H.
Abstract:: The development of micro total analysis systems (µTAS), also called “lab-on-a-chip”, or microfluidic analysis systems, is presented in this dissertation. Various research areas, covering subjects from magnetic particles synthesis to novel microchip fabrication techniques, are explored to develop a lab-on-a-chip system capable of performing magnetic bead-based bioassays. These devices are...
Resource Type:: Dissertation
Full Text:: collaborators, especially Dr. Daniela Hutanu and Dr. Cheryl Moody Bartel for their guidance during my

ScholarsArchive@OSU

Prediction and Measurement of Polycyclic Aromatic Hydrocarbons (PAHs) Transformation Products in the Environment.

Investigation of Chain Extension Approaches for the Stereoselective Reagent-Controlled Synthesis of alpha-Heteroatom Substituted Alkyl Boronic Esters

Development of novel analytical methods to detect emerging contaminants in aqueous environmental matrices using large-volume injection

Conformationally chiral diphenylethers and the enantioselective Ullmann etherification

Towards the Perfect Marriage Between Theory and Experiments in Drug Discovery and Synthesis : Insights into Structure Determination of Complex Natural Products and Mechanistic Understandings of Lactam Synthesis

C–H···O Non-Classical Hydrogen Bonding in the Stereomechanics of Organic Transformations: Theory and Recognition

Enigmatic Quantum Materials: Novel Spin-Orbit Coupled 4d/5d Metal Oxides and Intermetallics

Metal-oxo Clusters as Novel Photolithographic Materials: How Understanding the Chemistry of HafSOx Informs Next-Generation Patterning Systems

Iron and copper chalcogenides : photovoltaic absorber candidates and YZrF7 : a new upconversion host, Iron and copper chalcogenides : photovoltaic absorber candidates and YZrF₇ : a new upconversion host

Magnetic particles for selective extraction of trace analytes in microfluidic devices

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