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Filtering by: Creator Lockett, Daniel Edwin IV Academic Affiliation Chemistry Degree Level Doctoral

The kinetic and radiolytic aspects of control of the redox speciation of neptunium in solutions of nitric acid

Creator:

Precek, Martin

Abstract:

Neptunium, with its rich redox chemistry, has a special position in the chemistry of actinides. With a decades-long history of development of aqueous separation methods for used nuclear fuel (UNF), management of neptunium remains an unresolved issue because of its not clearly defined redox speciation. Neptunium is present in two,...

Resource Type:

Dissertation

Full Text:

2.4.2 Uranium(IV
Kinetic studies of some thermal rearrangements

Creator:

Schatz, Bruce Stewart

Resource Type:

Dissertation

Full Text:

inde- pendent groups. Vogel, Kiefer and Roth succeeded in isolating bi- III IV cyclo- [4.2.0] -2
Certain aspects of electron and coupled energy transfer in cardiac muscle

Creator:

Kettman, John Rutherford

Abstract:

The first area of investigation involves the electron transport of sub-mitochondrial particles and their components. The second area is the synthesis of ATP and other energy linked reactions and components of the energy conservation and transfer apparatus. Investigations on the nature of the tetramethyl-p-phenylenediamine (TMPD) shunt indicated that tetrachlorohydroquinone (TCHQ)...

Resource Type:

Dissertation

Full Text:

2. NADH 131 C. Succinate -DPPH Reductase 132 D. NADH -DPPH Reductase 139 Part IV. The
The synthesis and chemistry of strained bicyclic systems

Creator:

Scerbo, Louis

Abstract:

A facile route to bicyclo(2.1.1)hexanes was developed involving the intramolecular photocyclization of 1, 5-hexadien-3-one to bicyclo(2.1.1)hexan-2-one. A study of the chemistry of bicyclo-(2.1.1)hexan-2-one was undertaken. Deuterium exchange and borohydride reduction demonstrated the strain present in the ketone. Further evidence was obtained from the failure to introduce substituents alpha to the...

Resource Type:

Dissertation