Index Catalog // ScholarsArchive@OSU

CO₂ capture from wet flue gas using a water-stable and cost-effective metal-organic framework

Creator:: Loughran, Ryan P.
Abstract:: We report the use of MIL-120 as a water-stable and cost-effective metal-organic framework (MOF) for selectively capturing CO₂ from wet flue gas. Synthesized using inexpensive and environmentally benign reagents in water, MIL-120 possesses one-dimensional pores decorated with hydroxyl-bridged Al(III) ions and benzene rings with an interstitial spacing of 4.78 Å....
Resource Type:: Masters Thesis
Full Text:: : ______________________________________ Kyriakos C. Stylianou We report the use of MIL-120 as a water-stable and cost-effective metal

Electrochemistry at a reticulated vitreous carbon flow electrode

Creator:: Fahey, Jefferson Vincent
Abstract:: The electrochemistry of cadmium at a Reticulated Vitreous Carbon (RVC) electrode has been studied to determine the suitability of RVC as a working electrode for the electrochemical preconcentration of cadmium in the corrosive environment of zirconium dissolved in hydrofluoric acid. The electrochemistry in this investigation deals with deposition of solid...
Resource Type:: Masters Thesis
Full Text:: nucleation and no over potential effects. Cadmium, however, has a significant nucleation over potential at

Thermolysis of cis,cis,trans-1-phenyl-1,3,5-heptatriene

Creator:: Tilton, Mary Lehman
Abstract:: Isomerically pure cis,cis,trans-1-pheny1-1,3,5- heptatriene was prepared and cyclized. Ring closure was followed by a 1,5 hydrogen shift, and the only product observed was 1-phenyl -6-methyl -1,3-cyclohexadiene. Rough first order rate constants for thermolysis and the hydrogen shift were determined. Kinetic estimates indicate that the report of disallowed product in a...
Resource Type:: Masters Thesis
Full Text:: thermolysis and the hydrogen shift were determined. Kinetic estimates indicate that the report of disallowed

Low-Dose X-Ray Radiation Effects On the Proteomic Profiles of Hippocampus, Cortex, and Cerebellum of Contextual Fear Conditioning and Novel Object Recognition Trained Mice

Creator:: Koluda, Rony
Abstract:: Radiation exposure to the brain can occur from a variety of events, including space missions, nuclear accidents, and clinical treatments. The effects of high dose radiation are well studied, but those of lower dosage are more elusive. Decline of memory and cognition is observed in patients exposed to low dose...
Resource Type:: Masters Thesis
Full Text:: in contextual fear memory, while no effect is seen on novel object recognition. Mass spectrometric

Catalytic desymmetrization of D₂d̳-symmertic proprochiral tetrasubstituted biphenyl compounds: a novel approach to the synthesis of axially chiral C₂-symmetric molecules

Creator:: Gunderson, Jeremey Tyson
Abstract:: Many D2d-symmetric 2,2',6,6'-tetrasubstituted biphenyls are readily prepared via net oxidative dimerization of appropriate 1,3-disubstituted benzenes. Conversion of such proprochiral compounds to useful C2-symmetric chiral biphenyls requires formal replacement of two substituents on opposing aryl ring units with alternate groups. This under exploited desymmetrization tactic has been demonstrated for the generation...
Resource Type:: Masters Thesis
Full Text:: reagent control, but no reports concerning its realization by a (potentially) more efficient

Ion-pair high pressure liquid chromatography techniques for the determination of quaternary ammonium compounds

Creator:: Starbuck, Brian J.
Abstract:: Quaternary Ammonium Compounds, Qams, are an important class of chemicals which present interesting challenges to analysts. This thesis reports results of investigations on uses of ion-pairing techniques for separations and detection of Qams. Special apparatus for post-column solvent extraction of liquid chromatographic eluates was developed as part of this work....
Resource Type:: Masters Thesis
Full Text:: drug. If administered orally, Qam drugs usually have almost no effect. However, if given

Towards the Perfect Marriage Between Theory and Experiments in Drug Discovery and Synthesis : Insights into Structure Determination of Complex Natural Products and Mechanistic Understandings of Lactam Synthesis

Creator:: Snyder, Kevin M.
Abstract:: In this report, three studies are presented that aid in the development of drug discovery and their synthesis. In each, the importance of the marriage between computations and experiments is highlighted. Continued efforts in this vein are essential for future efforts towards improving human health. The first case study investigated...
Resource Type:: Masters Thesis
Full Text:: -Yeon Cheong In this report, three studies are presented that aid in the development of drug

The oxidation of trimethylamine by copper (II) chloride

Creator:: Lane, Thomas Alfred
Abstract:: This research was on the irreversible oxidation of trimethylamine by copper(II) chloride, which takes place at temperatures of about 75° and higher. The coordination of trimethylamine by copper(II) chloride, which is a preliminary reaction to the oxidation, was studied at 0°. The coordination of trimethylamine by the potential reduction product,...
Resource Type:: Masters Thesis
Full Text:: earlier report by Peters, 32 who found no complex in this system. In the copper(II)-trimethylamine system

The synthesis of 4-OXO-3,3-dimethyl-3, 4-dihydrophenanthrene

Creator:: Imel, Arthur Madison
Resource Type:: Masters Thesis
Full Text:: involving no oxygen function migration. Thus two modes of rearrangement are open to a dienone: the one

Using Computational Methods to Elucidate Reaction Mechanisms for Copper Catalyzed Reactions

Creator:: Caspary, Katherine E.
Abstract:: In this report, two studies are presented that utilize computations to predict and elucidate the reaction mechanisms of two different copper catalyzed reactions. Each study provides insight into the various chemical transformations, as well as the how and why behind regioselectivity and isotopic selectivity. The importance of this research is...
Resource Type:: Masters Thesis
Full Text:: report, two studies are presented that utilize computations to predict and elucidate the reaction

ScholarsArchive@OSU

CO₂ capture from wet flue gas using a water-stable and cost-effective metal-organic framework

Electrochemistry at a reticulated vitreous carbon flow electrode

Thermolysis of cis,cis,trans-1-phenyl-1,3,5-heptatriene

Low-Dose X-Ray Radiation Effects On the Proteomic Profiles of Hippocampus, Cortex, and Cerebellum of Contextual Fear Conditioning and Novel Object Recognition Trained Mice

Catalytic desymmetrization of D₂d̳-symmertic proprochiral tetrasubstituted biphenyl compounds: a novel approach to the synthesis of axially chiral C₂-symmetric molecules

Ion-pair high pressure liquid chromatography techniques for the determination of quaternary ammonium compounds

Towards the Perfect Marriage Between Theory and Experiments in Drug Discovery and Synthesis : Insights into Structure Determination of Complex Natural Products and Mechanistic Understandings of Lactam Synthesis

The oxidation of trimethylamine by copper (II) chloride

The synthesis of 4-OXO-3,3-dimethyl-3, 4-dihydrophenanthrene

Using Computational Methods to Elucidate Reaction Mechanisms for Copper Catalyzed Reactions

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