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Creator:: Hahne, Jeffrey A.
Abstract:: The carbon is photoelectron spectrum of CO₂ has been measured with very high photon energy resolution. The natural lifetime of the carbon is hole state has been determined from a series of spectra taken at photon energies of 308, 320, and 330 eV. The measured values of the lifetimes show...
Resource Type:: Masters Thesis
Full Text:: U. Hergenhahn 42 4.1 Electronic structure calculations, and experimental values, for CO2 and

Creator:: Carroll, Thomas X., Zahl, Maria G., Børve, Knut J., Sæthre, Leif J., Decleva, Piero, Ponzi, Aurora, Kas, Joshua J., Vila, Fernando D., Rehr, John J., and Thomas, T. Darrah
Abstract:: Carbon 1s photoelectron spectra for 2-butyne (CH3C CCH3) measured in the photon energy range from threshold to 150 eV above threshold show oscillations in the intensity ratio C2,3/C1,4. Similar oscillations have been seen in chloroethanes, where the effect has been attributed to EXAFS-type scattering from the substituent chlorine atoms. In...
Resource Type:: Article
Full Text:: ionization of the 1σ u orbital in ethyne. A strong shape reso- nance at k ≈ 1 a.u. is predicted to be a

Creator:: Kukk, E., Travnikova, O., Mondal, S., Kimura, M., Sakai, K., Miron, C., Martín, F., Ueda, K., Ayuso, D., Thomas, T. D., Decleva, P., Patanen, M., Argenti, L., Plésiat, E., Palacios, A., and Kooser, K.
Abstract:: We report an experimental and theoretical study of single-molecule inner-shell photoemission measured over an extended range of photon energies. The vibrational intensity ratios I (nu = 1)/I (nu = 0) from the C 1s photoelectron spectra of carbon monoxide, although mostly determined by the bond length change upon ionization, are...
Resource Type:: Article
Full Text:: , M. Neeb, M. N. Piancastelli, U. Hergenhahn, and A. M. Bradshaw, J. Phys. B 30, L741 (1997). 033412

Creator:: Allen, Scott E.
Abstract:: A series of compounds, 7-8 and 20-25, were tested as competitive inhibitors of 2,5-dihydroxyacetanilide epoxidase I (DHAE I) and DHAE II. A Hammett plot was constructed for each enzyme to determine the effect of electron density on inhibition. DHAE I gave a linear, highly correlated plot (r²=0.91) that signifies the...
Resource Type:: Dissertation

Creator:: Parker, Bethany A.
Abstract:: Per- and polyfluoroalkyl substances (PFAS) are a group of contaminants of great concern due to their toxicity and ubiquity in the environment. Remediation efforts historically have focused on granular activated carbon (GAC) because of its low maintenance and relatively low cost. However, GAC is not PFAS selective and is especially...
Resource Type:: Dissertation
Full Text:: . Buck, R. C.; Franklin, J.; Berger, U.; Conder, J. M.; Cousins, I. T.; De Voogt, P.; Jensen, A

Creator:: Shaw, Subrata
Abstract:: This thesis describes the development of a new enantioselective synthetic method employing chiral cis-2,5-diaminobicyclo[2.2.2]octane-based organometallic catalysts. The significance of this new method to organic synthesis is illustrated with preparation of enantioenriched products that are transformed to important pharmaceutical agents. Chapter 1 provides a brief historical overview of asymmetric catalysis, especially...
Resource Type:: Dissertation
Full Text:: Acta, 1991,1078, 411. 5. Blaser, H. U. Chem. Rev. 1992, 92, 935. 6. (a) De Vries, J. G. Encyclopedia

Creator:: Coville, Mary
Resource Type:: Dissertation
Full Text:: principally by two research groups the University of Uppsala group, notably U. Gelius and S. Svensson, and

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