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Filtering by: Creator Parra, Gabriel I. Remove constraint Creator: Parra, Gabriel I. Academic Affiliation Chemistry Remove constraint Academic Affiliation: Chemistry Non-Academic Affiliation Oregon State University. Graduate School Remove constraint Non-Academic Affiliation: Oregon State University. Graduate School

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Studies on oxidative dissimilation in Acetobacter suboxydan

Creator:

Hauge, Jens Gabriel

Resource Type:

Dissertation

Full Text:

TABLE OF CONTßÌ4T3 Jubject Page Introduction. . . . . . . . . . . . . . . . . . . . i tatorials
Part I: Synthetic Studies toward C10-functionalized Lycopodium Alkaloids. Part II: Exploration of the Pummerer Cyclization and Its Application to the Total Syntheses of the Abietane Diterpenoids

Creator:

Li, Xin

Abstract:

This dissertation is separated into two parts according to the two major distinct research projects. In Part I, the full account of synthetic studies toward C10-functionalized lycopodium alkaloids is described. In Part II, the detailed discussion on the exploration of the Pummerer cyclization methodology and its application to the total...

Resource Type:

Dissertation

Full Text:

on January 28 2019. Title: Part I: Synthetic Studies toward C10-functionalized Lycopodium
A study of the permanganate oxidation of 4-methylpyrimidine to pyrimidine-4-carboxylic acid

Creator:

Ni, Rain Wo

Abstract:

The yields from the oxidation of 4-methylpyrimidine with potassium permanganate were found to increase from 25 to 92 percent by the addition of small amount of potassium hydroxide to the reaction mixture. Pyrimidine-4-carboxylic acid decarboxylates in hot aqueous solution to yield pyrimidine and carbon dioxide. The rate is that decarboxylation...

Resource Type:

Masters Thesis

Full Text:

permanganate oxidation as reported by Gabriel, Several derivatives of pyrimidine-4-carboxylic acid were
Studies toward the total synthesis of alkaloids : nagelamide A and D, agelastatin D, dragmacidin A-C, salacin and almazoles

Creator:

Tonsiengsom, Sorasaree

Abstract:

Studies toward the total syntheses of highly potent cytotoxic alkaloids including the bromopyrrole alkaloids and indole alkaloids were conducted and are described. Studies carried out in the course of this dissertation consist of five total syntheses of natural products that include bromopyrrole alkaloids nagelamide A, D and agelastatin D as...

Resource Type:

Dissertation

Full Text:

and Gabriel-Robinson oxazole synthesis with chiral, nonracemic keto amides. An integral aspect of
A study of the limitations of ultraviolet spectral data for the determination of dissociation constants of organic nitrogeneous bases

Creator:

Vachananda, Sookapracha

Abstract:

Ultraviolet spectroscopic methods for the determination of dissociation constants can only be applied to those compounds having protonatable sites conjugated with or inherent in a chromophoric group of the compound. The determination of the dissociation constants of organic nitrogeneous bases by ultraviolet spectroscopic methods was found to be only reliable...

Resource Type:

Dissertation

Full Text:

heterocycle. With such compounds both methods, (I) those based on taking the extinction coefficient
The synthesis and cyclization of 2,4-diaminobutyric acid

Creator:

Li, Chun-wing

Abstract:

The objectives of this study were to isolate 2, 4-diaminobutyric acid and to attempt cyclizing the acid and its disulfonamide derivative. The original synthetic method by Adamson was followed but a modified isolation procedure for the acid was employed. Following the synthesis, the acidic solution was passed through Dowex-3 ion-exchange...

Resource Type:

Masters Thesis

Full Text:

anhydride was employed, I-acety1-3-acetamido- 2-pyrrolidone was obtained in very low yield. The
Stereospecific Synthesis of Stereotriad Motifs and Alkenes Using Enantioenriched sp³-Hybridized Carbenoids

Creator:

Xun, Sun

Abstract:

Enantioenriched sp³-hybridized carbenoid reagents CR1R2MX (X = nucleofuge, M = electrofuge) of different types were investigated for the synthesis of polysubstituted alkyl chains by iterative stereospecific reagent-controlled homologation (StReCH) and for the stereospecific connective synthesis of alkenes by eliminative cross-coupling. In the first part, putative enantioenriched α-chloroalkyllithiums (CHRLiCl) were employed...

Resource Type:

Dissertation

Full Text:

proceeds by a pair of fundamental steps both of which are inherently stereospecific: (i) electrophilic
Stereoselective synthesis & application of enantioenriched main group α-haloalkyl organometal reagents

Creator:

Emerson, Christopher R.

Abstract:

Sulfoxide-ligand exchange (SLE) and asymmetric halogen-metal exchange (AHME) processes were separately examined for the enantioselective synthesis of functionalized alpha-haloalkylmetal (carbenoid) reagents. Carbenoids derived from SLE were used to effect stereospecific reagent-controlled homologation (StReCH) of boronic esters and those generated via AHME were engaged in Darzens-type chemistry with aldehydes. Abstract for...

Resource Type:

Dissertation

Full Text:

of: acid chloride formation [(COCl)2 and cat. DMF)], aminolysis (with R2NH, R = Me, Et, i-Pr; 65
Removal of Radioactive Strontium, Iodine, and Uranium from Contaminated Groundwater : Sorption Processes and Properties

Creator:

Leonard, Mary E.

Abstract:

Iodine-129 is a key risk driver at sites where nuclear materials have been fabricated or processed, and it is a predominant isotope of concern in long-term waste storage strategies. I-129 exists primarily as iodate in the subsurface at the Hanford Site in south-central Washington State. Between 15 and 40% of...

Resource Type:

Dissertation

Full Text:

strategies. I-129 exists primarily as iodate in the subsurface at the Hanford Site in south-central
Total synthesis of indole alkaloids: pt. 1. Asymmetric synthesis of (-)-ibogamine. pt. 2. An approach toward the synthesis of koumine

Creator:

Choi, Younggi

Abstract:

PART I. The preparation of (-)-ibogamine (1) in fourteen steps from benzoquinone and in 10% overall yield is a powerful illustration of the value of the asymmetric Diels-Alder reaction as a starting point in a multistep synthesis. All four cycloadducts, 70, 77, 84 and 96, obtained with the (S)-BINOL-TiCl₂ complex...

Resource Type:

Dissertation

Full Text:

INDOLE ALKALOIDS: PART I. ASYMMETRIC SYNTHESIS OF (-)-IBOGAMINE. PART II. AN APPROACH TOWARD THE

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Academic Affiliation

Chemistry[remove]40

Advisor

Christensen, Bert E.10
Wickman, H. Hollis4
Christensen, B. E.3
White, James D.3
Blakemore, Paul1
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Commencement Year

Commencement Year range begin – Commencement Year range end

Current results range from 1937 to 2019

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Committee Member

Gable, Kevin3
Blakemore, Paul R.2
Lerner, Michael2
Loesgen, Sandra2
Simonich, Staci2
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Creator

Adenuga, Adeniyi A.1
Aft, Harvey1
Bommier, Clement1
Carson, Bonnie L.1
Choi, Younggi1
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Date

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Current results range from 1937 to 2019

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Decade

2010-20198
2000-20093
1990-19991
1980-19895
1970-19794
1960-196912
1950-19596
1930-19391

Degree Field

Chemistry40

Degree Level

Doctoral27
Master's13

Degree Name

Doctor of Philosophy (Ph.D.)27
Master of Science (M.S.)13

File Format

application/pdf1

Language

English [eng]40

License

All rights reserved11

Non-Academic Affiliation

Oregon State University. Graduate School[remove]40

Peer Reviewed

No39

Resource Type

Dissertation27
Masters Thesis13

Rights Statement

Copyright Not Evaluated29
In Copyright11

Subject

Pyrimidines6
Chlorination2
Heterocyclic compounds2
Oxidation2
Reduction (Chemistry)2
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