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Evidence for a stepwise mechanism in the cycloreversion of rhenium diolates

Creator:: Ness, Stephanie L.
Resource Type:: Masters Thesis
Full Text:: Evidence for a stepwise mechanism in the cycloreversion of

Synthetic studies on indolic enamide natural products: 1. Total syntheses of coscinamide A, concinamide B and igzamide: 2. Synthetic studies towards the synthesis of halocyamine B

Creator:: Ma, Yuelong
Abstract:: The 3-substituded indolic enamide moiety has been found in many marine compounds over the past 20 years. These indolic enamides exhibit various biological properties such as cytotoxic, anthelmintic, antimicrobial and HW-inhibitory activities. Among these indolic enamides, some are (E)-enamides, like coscinamide A and coscinamide B, others are (Z)-configuration in their...
Resource Type:: Masters Thesis
Full Text:: Studies on Indolic Enamide Natural Products: 1. Total BYntheses of Coscinamide A, Concinamide B and

Elucidating the Origins of Trends and Selectivities of Organic Reactions through Computations and Data Analysis Techniques

Creator:: Richardson, H. Camille
Abstract:: In this dissertation, a novel method for analyzing computed transition states (TS) for organic reactions is disclosed. It introduces the use of localization-delocalization matrices as parameters in a linear free energy relationship to determine the transition state interactions responsible for differences in energy between the major and minor TS in...
Resource Type:: Dissertation
Full Text:: : ______________________________________________________ Paul Ha-Yeon Cheong In this dissertation, a novel method for analyzing

Designing chiral rhenium (VII) trioxo complexes

Creator:: Juniku, Rajan B.
Abstract:: The epoxide deoxygenation reaction is formally the reverse of theepoxidation reaction. Compared to epoxidation, which has reached its fullmaturity, epoxide deoxygenation has not been as intensively developed.Among the few deoxygenation reagents, a handful are catalytic in a metalcomplex, show high stereospecificity and operate under mild conditions. Acommon feature of all...
Resource Type:: Masters Thesis
Full Text:: ) Trioxo Complexes. Abstract Atrnroved: Kevin P. Gable The epoxide deoxygenation reaction is formally

Rhenium-catalyzed oxygen-atom transfer reactions : mechanism and applications

Creator:: Brown, Eric C.
Abstract:: In situ reduction of hydrido-tris-(3,5-dimethylpyrazolyl)borato(trioxo) rhenium(V) with triphenylphosphine or triethylphosphite leads to a reactive rhenium(V) species that catalytically deoxygenates epoxides at 75-105°C. The reaction is stereospecific, except for trans- and cis-butene oxide which formed minor amounts of the opposite isomer. A variety of different functional groups were tolerated and even...
Resource Type:: Dissertation
Full Text:: triethyiphosphite leads to a reactive rhenium(V) species that catalytically deoxygenates epoxides at 75-105°C. The

Direct atom transfer vs. ring expansion in reaction of rhenium oxo complexes with cyclooctene epoxides and episulfides

Creator:: Khownium, Kriangsak
Abstract:: The rhenium (V) complex Tp'ReO₂ (Tp' = hydrido-tris-(3,5- dimethylpyrazolyl)borate), generated in situ from PPh₃ reduction of Tp'Re0₃, reacts with small ring heterocycles such as epoxides and episulf ides. The strained trans-cyclooctene ring provides an unusual thermodynamic bias against direct atom transfer, but trans-cyclooctene oxide still produces substantial amounts of trans-cyclooctene....
Resource Type:: Masters Thesis
Full Text:: show a greater propensity for direct atom transfer; under catalytic conditions the eventual products

Mechanistic studies on Re(V) mediated C-O bond transformations

Creator:: Zhuravlev, Fedor
Abstract:: In situ, reduction of Cp*ReO₃ by PPh₃ to form (Cp*ReO)₂(μ-O)₂ allows catalytic deoxygenation of epoxides, however, conproportionation between Reⱽ and Reⱽᴵᴵ species to form clusters of ((Cp*Re)₃(μ-O)₆}²⁺(ReO₄⁻)2 and new compound {(Cp*Re)₃(μ²-O)₃(μ³-O⁾³ReO₃}⁺(ReO₄⁻) leads to removal of rhenium from the catalytic cycle and loss of activity, The epoxide deoxygenation mediated by (Cp*ReO)₂(μ-O)₂...
Resource Type:: Dissertation
Full Text:: AN ABSTRACT OF THE THESIS OF Fedor A. Zhuravlev for the degree

Synthesis, characterization, and reactivity of rhenium dithiodiolate and monothiodiolate complexes

Creator:: Chuawong, Pitak
Abstract:: The rhenium dithiodiolate, Hydrido-tris-(3 ,5-dimethyl- 1 -pyrazol yl) borato(ethane- 1 ,2-dithiodiolato)(oxo)rheni um(V), and Hydrido-tris-(3 ,5-dimethyl- 1 -pyrazolyl)borato(phenylethanedithiodiolato)(oxo)rhenium(V), were synthesized by reductive cyclocondensation of alkane-1,2-dithiols with Tp'Re0₃ in a one pot fashion. The rhemium monothiodiolate, Hydrido-tris-(3 ,5-dimethyl- 1 -pyrazolyl) borato(ethane- 1 ,2-monothiodiolato)(oxo)rhenium(V), and Hydrido-tris-(3 ,5- dimethyl- 1 -pyrazolyl)borato(propanemonothiodiolato)(oxo)rhenium(V), were also synthesized...
Resource Type:: Masters Thesis
Full Text:: Reactivity of Rhenium Dithiodiolate and Monothiodiolate Complexes. Abstract Approved: Kevin P. Gable The

Active site studies and design of ligands for affinity column separation of 2,5-dihydroxyacetanilide epoxidase (DHAE) I and II

Creator:: Allen, Scott E.
Abstract:: A series of compounds, 7-8 and 20-25, were tested as competitive inhibitors of 2,5-dihydroxyacetanilide epoxidase I (DHAE I) and DHAE II. A Hammett plot was constructed for each enzyme to determine the effect of electron density on inhibition. DHAE I gave a linear, highly correlated plot (r²=0.91) that signifies the...
Resource Type:: Dissertation
Full Text:: . Abstract approved Kevin P. Gable A series of compounds, 7-8 and 20-25, were tested as competitive

Mechanistic studies of metal oxide mediated oxidation via kinetic isotope analysis of pentamethylcyclopentadienyl rhenium diolate cycloreversion

Creator:: Phan, Thuy N.
Resource Type:: Masters Thesis
Full Text:: Analysis of Pentamethylcyclopentadienyl Rhenium Diolate Cyclo reve rs ion Abstract approved: Kevin P

ScholarsArchive@OSU

Evidence for a stepwise mechanism in the cycloreversion of rhenium diolates

Synthetic studies on indolic enamide natural products: 1. Total syntheses of coscinamide A, concinamide B and igzamide: 2. Synthetic studies towards the synthesis of halocyamine B

Elucidating the Origins of Trends and Selectivities of Organic Reactions through Computations and Data Analysis Techniques

Designing chiral rhenium (VII) trioxo complexes

Rhenium-catalyzed oxygen-atom transfer reactions : mechanism and applications

Direct atom transfer vs. ring expansion in reaction of rhenium oxo complexes with cyclooctene epoxides and episulfides

Mechanistic studies on Re(V) mediated C-O bond transformations

Synthesis, characterization, and reactivity of rhenium dithiodiolate and monothiodiolate complexes

Active site studies and design of ligands for affinity column separation of 2,5-dihydroxyacetanilide epoxidase (DHAE) I and II

Mechanistic studies of metal oxide mediated oxidation via kinetic isotope analysis of pentamethylcyclopentadienyl rhenium diolate cycloreversion

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