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Filtering by: Creator Barnes, Cheryl L. Academic Affiliation Chemistry Resource Type Article

C–H···O Non-Classical Hydrogen Bonding in the Stereomechanics of Organic Transformations: Theory and Recognition

Creator:

Johnston, Ryne C. and Cheong, Paul Ha-Yeon

Abstract:

This manuscript describes the role of non-classical hydrogen bonds (NCHBs), specifically C–H···O interactions, in modern synthetic organic transformations. Our goal is to point out the seminal examples where C–H···O interactions have been invoked as a key stereocontrolling element and to provide predictive value in recognizing future and/or potential C–H···O interactions...

Resource Type:

Article

Full Text:

. Am. Chem. Soc., 1920, 42, 1419–1433. 2 (a) L. Pauling, The nature of the chemical bond and the