Index Catalog // ScholarsArchive@OSU

Expanding the scope of a Diels-Alder approach to biaryl synthesis

Creator:: Schwartz, Johanna Perkins
Abstract:: A Diels-Alder approach to biaryls (DAB) has been applied towards the synthesis of highly substituted, programmable biaryl templates. Tri- and tetra-ortho-substituted biaryls can be produced in just three to four steps from commercially available materials utilizing the Diels-Alder [4+2] cycloaddition. The methods described herein will illustrate the ability of mono...
Resource Type:: Dissertation
Full Text:: , 12320. 5. Fukuyama, Y.; Asakawa, Y. J. Chem. Soc. Perkin Trans. 1 1991, 2737. 6. Levine, D. P

Synthesis and Solution Characterization of Metal-Oxo Photoresist Precursors

Creator:: Hutchison, Danielle C.
Abstract:: Metal-oxo clusters can be described as soluble pieces of metal-oxide frameworks. Currently, metal-oxo clusters are being considered as solution-based precursors for extreme ultraviolet (EUV, 13.5 nm) photoresist materials, which are a crucial component in the fabrication of microelectronic devices. Two different photoresist precursor systems have been investigated – alkyltin clusters...
Resource Type:: Dissertation

Application of laser spectroscopy to structure and dynamics of small molecular systems

Creator:: Bozlee, Brian J.
Abstract:: A variety of laser spectroscopic methods are employed in this thesis research for studies of CF₃NO, an interesting model photodissociative system, and for investigation of low energy rotations and vibrations of small molecules and low molecular weight clusters in free jet expansions. Nonradiative energy decay for electronically excited CF₃NO is...
Resource Type:: Dissertation
Full Text:: dynamics of small molecular systems AN ABSTRACT OF THE THESIS OF Brian J. Bozlee for the degree of

Mobile phase mass transfer in chromatographic beds of impermeable spheres

Creator:: Cluff, John Robert
Resource Type:: Dissertation
Full Text:: privacy Stephen J. Hawkes A study of mobile phase mass transfer (zone disper- sion)in packed beds of

Fate and transport of the surfactant linear alkylbenzenesulfonate in a sewage-contaminated aquifer

Creator:: Krueger, Carolyn J.
Abstract:: Linear alkylbenzenesulfonate (LAS) is the most widely used anionic surfactant in commercial detergent formulations. The environmental fate of LAS is of interest because of its disposal to wastewater treatment facilities and subsequent occurrence as a micropollutant in surface waters and groundwater. While LAS fate in wastewater treatment systems and surface...
Resource Type:: Dissertation
Full Text:: . L.; Gledhill, W. E.; Mieure, J. P.; Adamove, J. E.; Nielsen, A. M.; Perkins, H. 0.; Eckhoff, W. S

Chemical and statistical analyses of chondrules from the Mokoia (CV3) meteorite

Creator:: Schilk, Alan J.
Abstract:: Nearly 100 chondrules were extracted from -8.6g of the Mokoia (CV3) meteorite and have been analyzed by sequential instrumental neutron activation analysis (INAA). The resulting data were utilized in a comprehensive statistical characterization of these objects and, unlike similar investigations, virtually no loss of relevant data was incurred due to...
Resource Type:: Dissertation
Full Text:: Mokoia (CV3) meteorite AN ABSTRACT OF THE THESIS OF Alan J. Schilk for the degree of Doctor of

Analytical method development for the identification, detection, and quantification of emerging environmental contaminants in complex matrices

Creator:: Place, Benjamin J.
Abstract:: The development of analytical methods for emerging contaminants creates many unique challenges for analytical chemists. By their nature, emerging contaminants have inherent data gaps related to their environmental occurrence, fate, and impact. This dissertation is a compilation of three studies related to method development for the structural identification of emerging...
Resource Type:: Dissertation
Full Text:: J. Place for the degree of Doctor of Philosophy in Chemistry presented on July 23, 2012. Title

Probing Aqueous Ion-Pairing and Speciation of Group V Polyoxometalates

Creator:: Sures, Dylan J.
Abstract:: Polyoxometalates are discrete anionic oxo clusters of the Group V and VI transition metals that can be conceptualized as molecular metal oxides. Because they are pairable with any alkali cation, a great deal of fundamental chemistry can be gleaned from their study, including solubility trends and insight into cation binding...
Resource Type:: Dissertation
Full Text:: AN ABSTRACT OF THE DISSERTATION OF Dylan J. Sures for the

Computational Investigations of Transition Metal Catalyses and Amorphous Metal Oxides : Accelerating Scientific Discovery Through Automation

Creator:: Mustard, Thomas J. L.
Abstract:: Automation of computational chemistry, while only an engineering feat, has the potential to accelerating computational research be removing all by the science. The work in this thesis mainly discusses fundamental understanding of complex chemical systems. What is not obvious are the numerous tasks necessary for this fundamental understanding. Under the...
Resource Type:: Dissertation
Full Text:: OF Thomas J. L. Mustard for the degree of Doctor of Philosophy in Chemistry presented on April

Reaction Pathways of Oxo-Hydroxo Group 5 Clusters to Metal Oxide Thin Films

Creator:: Mansergh, Ryan H.
Abstract:: Oxo-hydroxo Group 5 metal clusters are an untapped resource to study and advance aqueous solution processing of metal oxide thin films. The tetramethylammonium (TMA) hexatantalate salt (TMA6[H2Ta6O19]) yields dense Ta2O5 films (~95% of the bulk ß-Ta2O5 density) with atomically smooth surfaces (<4 Å root mean square surface roughness). This same...
Resource Type:: Dissertation
Full Text:: . Abstract approved: _____________________________________________________ Douglas A. Keszler Brady J

ScholarsArchive@OSU

Expanding the scope of a Diels-Alder approach to biaryl synthesis

Synthesis and Solution Characterization of Metal-Oxo Photoresist Precursors

Application of laser spectroscopy to structure and dynamics of small molecular systems

Mobile phase mass transfer in chromatographic beds of impermeable spheres

Fate and transport of the surfactant linear alkylbenzenesulfonate in a sewage-contaminated aquifer

Chemical and statistical analyses of chondrules from the Mokoia (CV3) meteorite

Analytical method development for the identification, detection, and quantification of emerging environmental contaminants in complex matrices

Probing Aqueous Ion-Pairing and Speciation of Group V Polyoxometalates

Computational Investigations of Transition Metal Catalyses and Amorphous Metal Oxides : Accelerating Scientific Discovery Through Automation

Reaction Pathways of Oxo-Hydroxo Group 5 Clusters to Metal Oxide Thin Films

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