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Filtering by: Creator Muehlbauer, Jeffrey D. Remove constraint Creator: Muehlbauer, Jeffrey D. Academic Affiliation Chemistry Remove constraint Academic Affiliation: Chemistry Subject Bicyclic compounds Remove constraint Subject: Bicyclic compounds

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  • Synthesis of some bicyclo[6.1.0] - nonane derivatives

    Creator:
    Wall, Robert Gene
    Abstract:
    Bicyclo [6.1.0] non-4-ene was prepared by two routes; (1) reaction of cis-cis-1, 5-cycloöctadiene with methylene iodide and zinc-copper couple, (2) sodium-methanol reduction of 9, 9-dibromobicyclo-[6.1.0] non-4-ene. The bicyclononene was characterized by its infrared spectrum, nuclear magnetic resonance spectrum and common physical properties. The olefin was hydrogenated to bicyclo [6.1.0] -...
    Resource Type:
    Masters Thesis
    Full Text:
    + + OH CH2 O 0,d, CH + + H CHO None of the identified products require a transannular reaction

  • Conformation and reactivity studies of some bicyclo(3.3.1) nonane derivatives

    Creator:
    Sturmer, David Michael
    Abstract:
    New syntheses for 2-bicyclo(3.3.1)nonanone and 7-bicyclo-(3.3.1)nonen-2-one were developed. The saturated ketone was prepared from phenol and acrylonitrile via a novel intramolecular S[subscript N]2 cyclization process. A Friedel-Crafts cyclization of 3-(3-cyclohexenyl)propanoyl chloride permitted synthesis of the unsaturated ketone from 4-cyclohexene carboxaldehyde. The formation of the bicyclo(3.3.1)nonane rather than a bicyclo(3.2.2)nonane skeleton...
    Resource Type:
    Dissertation
    Full Text:
    )Nonane Derivatives AN ABSTRACT OF THE THESIS OF DAVID MICHAEL STURMER for the Ph. D. in Chemistry