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Intramolecular transfer of complexed radicals as a possible explanation for long-range substituent effects observed in hydrogen abstraction reactions

Creator:: Newkirk, David Dudley
Abstract:: The relative rates of hydrogen abstraction from 1-phenylalkanes and a,w-diphenylalkanes using N-bromosuccinimide and bromotrichloromethane were determined at 70°C. In both cases the reactions were photoinitiated. Only benzylic bromination was observed. The 1-phenylalkanes reacted with both reagents to give rates largely independent of substrate. Similarly, the rate of the reaction between...
Resource Type:: Dissertation
Full Text:: 1-phenylalkanes and a,w-diphenylalkanes using N-bromosuccinimide and bromotri- chloromethane were

The Robinson-Mannich base synthesis applied to substituted acetoacetic ester

Creator:: LaPore, Richard Francis
Resource Type:: Dissertation
Full Text:: over t o hour period . 1tb1n a few minutes after th slurry w s initially introduced the reaction

The reaction of N-bromosuccinimide (I) with acetals

Creator:: Joncich, Micheal Joseph
Resource Type:: Masters Thesis
Full Text:: of the volatile o products, the acetal w distilled, b. p. 102 - 104 u.; fl20 1.3820; weiht 70.8

Steroid-dihalocarbene reactions

Creator:: Damewood, John Roderick
Abstract:: Dihalocarbenes have been generated by thermal decomposition of sodium trichloroacetate and tribromomethylphenylmercury, and give mono dihalocyclopropyl adducts with steroid dienes. Such compounds offer an easy starting point for the synthesis of unusual derivatives of potential biological interest. Under the same conditions, however, addition to non-conjugated double bonds does not take...
Resource Type:: Masters Thesis
Full Text:: addition reactions (6, 8, 39). However, so called carbene complexes, such as the Simmons -Smith reagent

Ion pair return phenomena in the thermal decomposition of aralkyl thiocarbonates

Creator:: Scriven, Roger Louis
Resource Type:: Dissertation
Full Text:: Bromobenzene 1.0 8.3 in equation 1. The results of these calculations for the decomposition O 018/2 (+) ROI

A study of the acid catalyzed rearrangement of 4-oxo-3, 3-dimethyl-3, 4-dihydrophenanthrene

Creator:: Imel, Arthur Madison
Resource Type:: Dissertation
Full Text:: ot dl~uttou. w!ll cause th• ~- ,0.-H t...,_ue110y to dl•ppear. It e1the~ ot the -•nols (XX) o~ (X

Decarboxylation studies on α-methyl-α-Phenylcaproic acid and some of its derivatives

Creator:: Sheppard, Dorothy Louise
Resource Type:: Masters Thesis
Full Text:: Chemische Gesellschaft. 39: 3067. 1906. 56. Stoughton, R. W. and Roger Adams. Stereochemistry of diphenyl

Catalysis of the isotopic exchange reaction between thionyl chloride and liquid sulfur dioxide

Creator:: Burge, David Edwin
Resource Type:: Dissertation
Full Text:: THIONYL CHLORIDE AND LIQUID SULFUR DIOXIDE DAVID EDWIN BIJRGE A THESIS submitted to O}ECON STATE

A study of factors leading to N, N-diacetylation of aminopyrimidines

Creator:: Carson, Bonnie L.
Abstract:: Although 4- and 5-diacetamidopyrimidines have been reported in the literature within the past eleven years, it was not until 1965 that a 2-diacetamidopyrimidine was reported. The current investigation was undertaken to determine whether other 2-diacetamidopyrimi-dines could be synthesized and what the effect of various nuclear substituents would be on the...
Resource Type:: Masters Thesis
Full Text:: 39 NH2 large excess(1) A NH2 16(1), 100(4) R 6. 5 50 NH2 16(1), 100(4) R 48 100 NH2 (4) A

Kinetics and mechanisms of nucleophilic displacement reactions with S-methyl-S-phenyl-sulfiminium perchlorate

Creator:: KiYokane, Richard Junji
Resource Type:: Masters Thesis
Full Text:: 2. 08 4. 78 O. 949 6. 08 0. 42 2. 39 O. 964 6. 08 1.96 2. 19 O. 936 8. 06 0. 98 2. 19 O. 953 8. 07 0

ScholarsArchive@OSU

Intramolecular transfer of complexed radicals as a possible explanation for long-range substituent effects observed in hydrogen abstraction reactions

The Robinson-Mannich base synthesis applied to substituted acetoacetic ester

The reaction of N-bromosuccinimide (I) with acetals

Steroid-dihalocarbene reactions

Ion pair return phenomena in the thermal decomposition of aralkyl thiocarbonates

A study of the acid catalyzed rearrangement of 4-oxo-3, 3-dimethyl-3, 4-dihydrophenanthrene

Decarboxylation studies on α-methyl-α-Phenylcaproic acid and some of its derivatives

Catalysis of the isotopic exchange reaction between thionyl chloride and liquid sulfur dioxide

A study of factors leading to N, N-diacetylation of aminopyrimidines

Kinetics and mechanisms of nucleophilic displacement reactions with S-methyl-S-phenyl-sulfiminium perchlorate

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