Index Catalog // ScholarsArchive@OSU

Applications of the Mannich reaction

Creator:: Bush, David Clair
Resource Type:: Dissertation
Full Text:: II CH2O CH3C000OH- I "NH2 ' This specIal type of Marmich reaction has been called the ïoebner

Intramolecular transfer of complexed radicals as a possible explanation for long-range substituent effects observed in hydrogen abstraction reactions

Creator:: Newkirk, David Dudley
Abstract:: The relative rates of hydrogen abstraction from 1-phenylalkanes and a,w-diphenylalkanes using N-bromosuccinimide and bromotrichloromethane were determined at 70°C. In both cases the reactions were photoinitiated. Only benzylic bromination was observed. The 1-phenylalkanes reacted with both reagents to give rates largely independent of substrate. Similarly, the rate of the reaction between...
Resource Type:: Dissertation
Full Text:: study and to Mr. J. C. Arnold and Mr. D. F. Church for many helpful discussions. A very special thanks

Decarboxylation studies on α-methyl-α-Phenylcaproic acid and some of its derivatives

Creator:: Sheppard, Dorothy Louise
Resource Type:: Masters Thesis
Full Text:: prevent hydrolysis of the silver salt to the free acid. Brookenmiiller and Hoffman (10) report an 80

Studies of the mechanism of the disproportionations of sulfinic acids and disulfides

Creator:: Fitzgerald, Alvin
Resource Type:: Masters Thesis
Full Text:: ). Detoni and Hadzi (21) report that this peak is not due to an S -H bond, but that it is due to very

A study of factors leading to N, N-diacetylation of aminopyrimidines

Creator:: Carson, Bonnie L.
Abstract:: Although 4- and 5-diacetamidopyrimidines have been reported in the literature within the past eleven years, it was not until 1965 that a 2-diacetamidopyrimidine was reported. The current investigation was undertaken to determine whether other 2-diacetamidopyrimi-dines could be synthesized and what the effect of various nuclear substituents would be on the...
Resource Type:: Masters Thesis
Full Text:: diacylamines may be found in the 1956 report of Cadwallader and La Rocca (27). These investigators cited

An application of the Mannich reaction in the preparation of a substituted ketoöctalin

Creator:: LaPore, Richard Francis
Resource Type:: Masters Thesis
Full Text:: cyclohexanone and for- maldehyde. Upon the basis of their report it was decided to attempt a preparation of

Decomposition of di-p-toluenesulfonyl-hydrazones

Creator:: Bradway, Diane Elizabeth
Abstract:: Thermal decomposition of several di-p-toluenesulfonylhydrazones was studied. It was found that the carbene decomposition of tetramethyl-1,3-cyclobutanedione, di-p-toluenesulfonylhydrazone gave two products resulting from rearrangement. One was identified as 2,5-dimethyl-1,3,4-hexatriene. A tentative structure for the second was proposed. During the course of the study, a more convenient procedure for thermal decompositions was...
Resource Type:: Masters Thesis
Full Text:: from Sodium I'{ethoxide-Special Care Taken in DrYing Decomposition in Presence of a Proton Source Bamf

Methanolysis of tetrakis(trichlorophosphine)nickel(0)

Creator:: Bachman, David Franklin
Abstract:: The methanolysis of phosphorus trichloride coordinated to nickel (0) has been studied. Free phosphorus trichloride reacts with methanol to give dimethyl hydrogen phosphonate, methyl chloride, and hydrogen chloride. The reaction involves a rearrangement on phosphorus using the lone pair, in which the coordination number increases from three to four. In...
Resource Type:: Masters Thesis
Full Text:: extended. Special thanks go to Messrs. G. Gathercoal, O. Barnes, and C. Brown; Mrs. B. Clausen and Mrs

Catalysis of the isotopic exchange reaction between thionyl chloride and liquid sulfur dioxide

Creator:: Burge, David Edwin
Resource Type:: Dissertation
Full Text:: separation and purification of the sulfur-35 is described in a later section of this report (see

The study of the influence of the nitro substituent on the hydrazinolysis of certain substituted 5-nitropyrimidines

Creator:: Stahl, Quade Russell
Abstract:: The unique reaction between 4, 6-dimethoxy-5-nitropyrimidine and methylhydrazine was investigated. The reaction product was identified as 4-hydrazino-6-hydroxypyrimidine from (a) spectral data, (b) by direct synthesis of the product via 4-chloro-6-hydroxypyrimidine and hydrazine, and (c) by conversion of the product to the known 4-amino-6-hydroxypyrimidine using Raney nickel. The product was not...
Resource Type:: Dissertation

ScholarsArchive@OSU

Applications of the Mannich reaction

Intramolecular transfer of complexed radicals as a possible explanation for long-range substituent effects observed in hydrogen abstraction reactions

Decarboxylation studies on α-methyl-α-Phenylcaproic acid and some of its derivatives

Studies of the mechanism of the disproportionations of sulfinic acids and disulfides

A study of factors leading to N, N-diacetylation of aminopyrimidines

An application of the Mannich reaction in the preparation of a substituted ketoöctalin

Decomposition of di-p-toluenesulfonyl-hydrazones

Methanolysis of tetrakis(trichlorophosphine)nickel(0)

Catalysis of the isotopic exchange reaction between thionyl chloride and liquid sulfur dioxide

The study of the influence of the nitro substituent on the hydrazinolysis of certain substituted 5-nitropyrimidines

Limit your search

Academic Affiliation

Advisor

Commencement Year

Creator

Date

Decade

Degree Field

Degree Level

Degree Name

Language

Non-Academic Affiliation

Peer Reviewed

Resource Type

Rights Statement

Subject

Search Constraints

Search Results

Limit your search