Index Catalog // ScholarsArchive@OSU

A pyrolysis of cis-1-trimethylsiloxy-1-cyclopropyl-3-cyclononene : the thermal isomerization of 2-phenyl-1-trimethylsiloxy-1-vinylcyclononane

Creator:: Choi, Young Bok
Abstract:: Part 1 The pyrolysis of cis-1-trimethylsiloxy-1-cyclopr opyl-3-cyclononene in the temperature range 285-350° is described. Instead of siloxy-Cope rearrangement, undesired desiloxylation took place. Part 2 Gas-phase pyrolytic rearrangement of 2-phenyl-1-trimethylsiloxy-1-vinylcyclononane was investigated in a static system in the temperature range 213-330°. It was discovered that three major products resulted: cis- and...
Resource Type:: Masters Thesis
Full Text:: Redacted for privacy Dr. Richard W. Thies The pyrolysis of cis -1 tr imethyls iloxy- 1 - cyclopr opyl- 3

Cyclization of organolithium and -zirconium compounds ; Rearrangements of selected anionic compounds in highly disassociative solvents

Creator:: Bass, Lawrence W.
Abstract:: Intramolecular cyclization of organometallic compounds represents a promising tool for synthesis. The reaction involves exothermic consumption of intramolecular double bonds via insertion into a carbon metal sigma bond. This represents an intramolecular example of the reaction type responsible for metal catalyzed polymerization of olefins. Organolithium reagents were found to cyclize...
Resource Type:: Dissertation
Full Text:: ABSTRACT OF THE THESIS OF Larry W. Bass for the degree of Doctor of Philosophy in Chemistry presented on

Synthesis of 1, 4-dihydroxybutanedione and certain derivatives of dl-2-deoxytetrose

Creator:: Fowlks, William Louis
Resource Type:: Dissertation
Full Text:: CNde product was redlatllled through a .W em. VI g r e u x co I u m n • The fraction balling 45-S()O

Studies toward the synthesis of halichlorine and pinnaic acid

Creator:: Korf, Eric A.
Abstract:: Three approaches toward the core of halichlorine and pinnaic acid are described. The first approach entails a racemic transannular nitrone-olefin [3+2] cycloaddition from nitrone 238. Construction of the nitrone 238 began with aldehyde 241. Another key feature in this route involved a ring-closing metathesis for the formation of a 14-membered...
Resource Type:: Dissertation
Full Text:: of halichlorine……..…….39 1.4.17. Ihara’s approach to the bicyclic core of halichlorine

Total synthesis of (+)-bourgeanic acid and conformational analysis of its dilactone

Creator:: Johnson, Alan T. (Alan Thomas), 1957-
Resource Type:: Dissertation
Full Text:: must also thank my parents, Carl and Mary, for their support and for giving me the opportunity to

Part I: Synthetic Studies toward C10-functionalized Lycopodium Alkaloids. Part II: Exploration of the Pummerer Cyclization and Its Application to the Total Syntheses of the Abietane Diterpenoids

Creator:: Li, Xin
Abstract:: This dissertation is separated into two parts according to the two major distinct research projects. In Part I, the full account of synthetic studies toward C10-functionalized lycopodium alkaloids is described. In Part II, the detailed discussion on the exploration of the Pummerer cyclization methodology and its application to the total...
Resource Type:: Dissertation
Full Text:: different cell lines.11 Figure 1.1: Lycopodine – the First Isolated Lycopodium Alkaloids N O

Chemical and biochemical studies of the Lactobacillus bulgaricus factor

Creator:: Stewart, Charles Jack
Resource Type:: Masters Thesis
Full Text:: of Autoclav1ng on Growth Promotion by (3 •Aletheine 12 'fable III Release o~ ound Pantothenic

The synthesis and valence isomerization of some para-substituted 1-phenyl-1,3,5-hexatrienes

Creator:: Platt, James LeGrande
Resource Type:: Dissertation
Full Text:: -CaCMgBr X N(CH 3 )3 X. X OH O PC15 EtMgBr CH t=CH-CEC-CH 2CH 2.0H Zo p-Tosyl Cl N(CH3)3 KNH2

Semihydrogenation in conjugated systems and its application in the synthesis of trienes

Creator:: Tashiro, John Toshiyuki
Resource Type:: Dissertation
Full Text:: ,CH2 251 261 271 3. 7 4.6 13 3.4 CH3 -CHt CH-CHt CH-CHtCH-CH2OH 264.5 5.30 39 - CHt CH -O O

The intramolecular cyclization of organoaluminum compounds ; Reductions using low-valent titanium and zirconium complexes

Creator:: Chum, Pak-Wing
Resource Type:: Dissertation
Full Text:: .?NzNN7NNN 8 2 a --o Toluene 3 olvent solvent O 5a a kinetic result rather than a thermodynamic one

ScholarsArchive@OSU

A pyrolysis of cis-1-trimethylsiloxy-1-cyclopropyl-3-cyclononene : the thermal isomerization of 2-phenyl-1-trimethylsiloxy-1-vinylcyclononane

Cyclization of organolithium and -zirconium compounds ; Rearrangements of selected anionic compounds in highly disassociative solvents

Synthesis of 1, 4-dihydroxybutanedione and certain derivatives of dl-2-deoxytetrose

Studies toward the synthesis of halichlorine and pinnaic acid

Total synthesis of (+)-bourgeanic acid and conformational analysis of its dilactone

Part I: Synthetic Studies toward C10-functionalized Lycopodium Alkaloids. Part II: Exploration of the Pummerer Cyclization and Its Application to the Total Syntheses of the Abietane Diterpenoids

Chemical and biochemical studies of the Lactobacillus bulgaricus factor

The synthesis and valence isomerization of some para-substituted 1-phenyl-1,3,5-hexatrienes

Semihydrogenation in conjugated systems and its application in the synthesis of trienes

The intramolecular cyclization of organoaluminum compounds ; Reductions using low-valent titanium and zirconium complexes

Limit your search

Academic Affiliation

Advisor

Commencement Year

Committee Member

Creator

Date

Decade

Degree Field

Degree Level

Degree Name

File Format

Language

License

Non-Academic Affiliation

Peer Reviewed

Resource Type

Rights Statement

Subject

Search Constraints

Search Results

Limit your search