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Creator:: James, Corinne Patricia
Abstract:: The potassium salts of certain 1-vinylcycloalk-3-en-l-ols have been found to undergo sigmatropic ring expansion rearrangements in HMPA. Preliminary investigations of several benzo-substituted medium ring systems were undertaken in order to determine which of these was best suited for further study. A synthetic sequence leading to the formation of 5-methy1-6-viny1-7,8,9,10-tetrahydro-6-benzocyclo-octenol, which...
Resource Type:: Masters Thesis
Full Text:: Sigmatropic Ring Expansion Reactions Abstract approved: Redacted for Privacy Richard W. Thies The potassium

Creator:: Chiarello, Ronald Harry
Resource Type:: Dissertation
Full Text:: TOWARD THE SYNTHESIS OF LARGE RING HORMONE ANALOGS Abstract approved: Redacted for privacy Richard W

Creator:: Provant, Stephen Glenn
Abstract:: 3-Methyl-2,4-dioxabicyclo [3.3.1] nonane and 7-hydroxy-3-methyl-2, 4-dioxabicyclo [3.3.1] nonane were synthesized by the method of Croxall, Glavis and Neher, although in low yields. The structure of both compounds was proven by analytical methods and analysis of their spectral properties. Tentative configuration of C-3 in both compounds was assigned on the assumption...
Resource Type:: Masters Thesis
Full Text:: and W-instein. 17 EXPERIMENTAL I , 3 - Cyclohexanediol 1,3-Cyclohexaned.iol was prepared, b.p

Creator:: Li, Thomas Hoi-chow
Resource Type:: Dissertation
Full Text:: doubly charged ion as shown here, participation by the lone pair would be impossible. 42 [Phx W Ph

Creator:: Salisbury, Kirby Grant
Abstract:: 2-Carboxy-3(3-cyclohexen-1-yl)propionic acid, 3-(3-cyclohexen-1-yl)propionic acid and 3-(3-cyclohexen-1-yl)propionyl chloride were prepared in sequence from ethyl-2-carbethoxy-3-(3-cyclohexen-1-yl)propionate. Cyclization of 3-(3-cyclohexen-1-yl)propionic acid in polyphosphoric acid resulted in the formation of 4, 5, 6, 7-tetrahydroindanone which was identified by its ultraviolet spectrum and its physical properties. 7-Bicyclo[3.3.1] nonen-2-one was prepared by a Friedel-Crafts cyclization of 3-(3-cyclohexen-1-yl)-propionyl...
Resource Type:: Masters Thesis
Full Text:: azabicyclic ketones. Journal of the American Chemical Society 84:3139 -3147. 1962. 14. Johnson, W. S. et al

Creator:: Raghavan, Ramaswamy Srinivasa, 1941-
Resource Type:: Dissertation
Full Text:: appreciation is expressed to Dr. Joseph N. Blazevich, Mr. Myrick W. Pullen III, Mr. James E. Billigmeier, and

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