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Creator:: Bythell, Benjamin James
Abstract:: The fragmentation characteristics of protonated peptides have been investigated using tandem mass spectrometry (MS/MS) under various fragmentation regimes and detailed density functional theory (DFT) reaction pathway calculations. The DFT calculations predict novel salt-bridge stabilized transition structures as well as consecutive reactions occurring in proton-bound dimers for some of the ions...
Resource Type:: Dissertation
Full Text:: 2 AN ABSTRACT OF THE DISSERTATION OF Benjamin James Bythell for the degree of Doctor of

Creator:: McRitchie, Donna Louise
Abstract:: This paper describes the synthesis of t-butyl bicyclo[7.1.0] decane-2-percarboxylate and its photolytic decomposition. The title compound was found to undergo simple homolytic cleavage when exposed to light of 2537 A; producing the cyclodecyl radical, carbon dioxide, and t-butoxy radical. The largest percentage of products arose from an intimate radical pair...
Resource Type:: Masters Thesis
Full Text:: . Poulter and Winstein (29) have suggested that rings of this size may even twist into unfavorable

Creator:: Reddy, Guvvala Nagabhushana
Abstract:: Studies were carried out to determine the absolute stereochemistry of botryococcene (1). The natural product was degraded to two sets of 'y- and 8- valerolactones. All enantiomeric variations of these lactones were synthesized in optically pure form starting from (S)- and (R)-methyloxiranes. 1H NMR correlation of natural and synthetic materials...
Resource Type:: Dissertation
Full Text:: proposed by Poulter (Fig. I.4),46 in which a central role is ascribed to chrysanthemyl pyrophosphate (15

Creator:: Somers, Todd Charles
Resource Type:: Dissertation
Full Text:: . Poulter at the University of Utah and its gross structure was assigned as 10 by application of 1H, 13C

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