Index Catalog // ScholarsArchive@OSU

Synthesis of metabolites from the ascomycetes : I. The synthesis and absolute configuration of leptosphaerin : II. Approaches to the synthesis of byssochlamic acid

Creator:: Pallenberg, Alexander J.
Abstract:: Part I. The total synthesis of (+)-leptosphaerin (2), a metabolite of the marine Ascomycete Leptosphaeria Oraemaris (Linder) was achieved, unambiguously establishing both the relative and absolute stereochemistry of this natural product. This synthesis also resolved the long-standing question of which of the isomeric structures 1 or 2 correctly represents the...
Resource Type:: Dissertation
Full Text:: AN ABSTRACT OF THE THESIS OF Alexander J. Pallenberg for the degree of Doctor of Philosophy in

High-resolution infrared studies of perdeutero-spiropentane, C₅D₈

Creator:: Erickson, Blake Alexander, Ju, X., Nibler, Joesph W., Beaudry, C. M., and Blake, T. A.
Abstract:: Perdeutero-spiropentane (C₅D₈) has been synthesized and infrared and Raman spectra are reported for the first time. Wavenumber assignments are made for most of the fundamental vibrational modes. Gas phase infrared spectra were recorded at a resolution (0.002 cm⁻¹) sufficient to resolve individual rovibrational lines and show evidence of strong Coriolis...
Resource Type:: Article
Full Text:: projection of J onto the symmetry axis, so that K = k. The D and H terms are quartic and sextic

Strategic Application of Computations to Diverse Chemical Systems

Creator:: Brueckner, Alexander C.
Abstract:: My work has focused on streamlining the study of organic compound structure, properties, and reactions by 1) understanding and using available computational software, 2) developing software packages to facilitate data manipulation as well as augment public programs, and 3) applying public and in-house developed software to further the understanding of...
Resource Type:: Dissertation
Full Text:: . New York, NY 2016 [3] Gaussian 09, Revision D.01, Frisch, M. J.; Trucks, G. W.; Schlegel, H. B

Satellite structure in the gas-phase X-ray photoelectron spectra of planar unsaturated molecules

Creator:: Chambers, Scott Alexander
Abstract:: The satellite structure ("shake-up") present in the X-ray photoelectron spectra of several planar molecules containing double bonds has been investigated in the gas phase. This set consists of three five-membered heterocyclic molecules, ethylene and two of its fluorinated analogs, and benzene with three of its fluorinated analogs. In addition, core...
Resource Type:: Dissertation
Full Text:: spectra of planar unsaturated molecules AN ABSTRACT OF THE THESIS OF DOCTOR OF SCOTT ALEXANDER CHAMBERS

Adsorption by strontium salts of traces of iron from caustic soda solutions

Creator:: Boyd, Charles Alexander
Resource Type:: Masters Thesis
Full Text:: reaction Fe(OP)3 + lClO -i- 20H-" FeO -i- 2tH2O -t- wa found to be equal to J,3j calorieg. These

The kinetics and mechanisms of the cleavage of some sulfur-sulfur bonds

Creator:: Favstritsky, Nicolai Alexander
Resource Type:: Dissertation
Full Text:: -sulfur bonds AN ABSTRACT OF THE THESIS OF NICOLAI ALEXANDER FAVSTRITSKY for the Ph. D. (Name) (Degree

Coriolis analysis of several high-resolution infrared bands of bicyclo[111]pentane-d₀ and -d₁

Creator:: Perry, A., Martin, M. A., Nibler, J. W., Maki, A., Weber, A., and Blake, T. A.
Abstract:: High-resolution infrared absorption spectra have been analyzed for two bicyclo[111]pentane isotopologues, C₅H₈ (-d₀) and C₅H₇D (-d₁), where in the latter the D-atom replaces a hydrogen on the C₃ symmetry axis such that the molecular symmetry is reduced from D₃ₕ to C₃ᵥ. Two (a"₂) parallel bands, v₁₇ and v₁₈, of bicyclopentane-d₀...
Resource Type:: Article
Full Text:: (8) ±0.491(17) w1,1 [±0.228] [0] 0.22 w1,1,J � 105 ±1.173(20)d w1,1,kl � 103 1.17(5)d # trans. 156

Studies towards the total syntheses of (+)-phomactins A, D and G

Creator:: Schwartz, Keith D.
Abstract:: Studies towards the total synthesis of (+)-Phomactin A (1), D (6), and G (9), fungal metabolites with unique molecular architecture and pronounced biological activity, are described. These studies resulted in the synthesis of advanced intermediates 354 and 356, which contain all of the carbon atoms of 1, 6 and 9....
Resource Type:: Dissertation
Full Text:: .; Matsushita, Y.; Iijima, Y. J. Med. Chem. 1996, 39, 5281-5284. 6 Goldring, W. P. D.; Alexander, S. P

N-D-Glucosylglycine in purine biosynthesis

Creator:: Rogers, Dexter, 1921-
Resource Type:: Dissertation
Full Text:: N-D-Glucosylglycine in Purine Biosynthesis N-D

LL-C10037α and MM 14201 : structure, biosynthesis and enzymology of two epoxysemiquinone antibiotics

Creator:: Shen, Ben
Resource Type:: Dissertation
Full Text:: 3.55 d 1' 169.5 s 2' 23.7 q 2.01 s 1655, 1545 J (Hz) 2.6, 2.7 2.7, 3.1, 6.4 2.7, 3.1, 4.2 6.1 4.1

ScholarsArchive@OSU

Synthesis of metabolites from the ascomycetes : I. The synthesis and absolute configuration of leptosphaerin : II. Approaches to the synthesis of byssochlamic acid

High-resolution infrared studies of perdeutero-spiropentane, C₅D₈

Strategic Application of Computations to Diverse Chemical Systems

Satellite structure in the gas-phase X-ray photoelectron spectra of planar unsaturated molecules

Adsorption by strontium salts of traces of iron from caustic soda solutions

The kinetics and mechanisms of the cleavage of some sulfur-sulfur bonds

Coriolis analysis of several high-resolution infrared bands of bicyclo[111]pentane-d₀ and -d₁

Studies towards the total syntheses of (+)-phomactins A, D and G

N-D-Glucosylglycine in purine biosynthesis

LL-C10037α and MM 14201 : structure, biosynthesis and enzymology of two epoxysemiquinone antibiotics

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