Index Catalog // ScholarsArchive@OSU

Porous metal-organic materials for gas capture

Creator:: Rookard, Tanner Daniel
Abstract:: Metal-organic polyhedra (MOPs) are discrete molecules comprised of a metal and interconnecting ligands. The resulting MOP structures are porous cages, and to date, they have shown great promise toward gas capture. Ammonia is a hazardous gas that is produced in enormous quantities for use in fertilizers. In this talk, I...
Resource Type:: Capstone Project
Full Text:: Paddle-Wheel Building Blocks. Journal of the American Chemical Society 2001, 123 (18), 4368- 4369. 17

New Graphite Intercalation Chemistry with Alkaline Earth Metals

Creator:: Xu, Wei
Abstract:: Novel graphite intercalation compounds (GICs) and associated chemistry have been explored, specifically: (1) containing alkyl- substituted imidazolium cations; (2) a series containing alkaline earth metal (Mg, Ca, Sr, Ba) cations with ethylenediamine (en) co-intercalates; (3) showing reversible intragallery M-M bonding and (4) via electrochemical intercalation of Mg cations with potential...
Resource Type:: Dissertation
Full Text:: experiments, and for leading me transfer into the materials division and Dr. Lerner’s research group; Dr

Synthesis of α-Ketoester- and α-Hydroxyester-Substituted Isoindazoles via the Thermodynamic Coarctate Cyclization of Ester-Terminated Azo-Ene-Yne Systems

Creator:: McClintock, Sean P., Forster, Nathan, Herges, Rainer, and Haley, Michael M.
Abstract:: The synthesis of isoindazoles bearing α-ketoester and α-hydroxyester groups via the coarctate cyclization of ester terminated azo-ene-yne precursors is described. Whereas previous studies on isoindazole formation have shown the reaction to proceed through a kinetic coarctate pathway, functionalization of the terminal acetylene with a methyl ester sufficiently stabilizes the carbene...
Resource Type:: Article
Full Text:: support of this research. S.P.M. acknowledges the NSF for an IGERT fellowship (DGE-0549503). N.F

Biochemical studies on a plant virus

Creator:: Kuehl, LeRoy Robert
Resource Type:: Masters Thesis
Full Text:: proteins in small amounts of blood serum and plasma. American journal of clinical pathology% technical

I. Isolation of certain toxic components of kraft mill waste and attempts to determine their structure. ; II. Studies of the mechanism of the cope rearrangement of 1,2-divinyl-1, 2-cyclohexanediol

Creator:: Banks, Richard Charles
Abstract:: PART I. A chemical examination of the materials toxic to fish in kraft pulp mill wastes has been made as part of a water pollution study. Thirty gallons of "foul condensate" from a typical kraft mill gave 14 g of organic material when extracted with methylene chloride, and an additional...
Resource Type:: Dissertation
Full Text:: of those compounds responsible for that toxicity. The research described in Part I of this thesis is

Radiolysis of succinic acid in water

Creator:: Tanaka, Fred Shigeru
Abstract:: The radiolysis of succinic acid in aqueous solutions induced by gamma irradiation from ⁶⁰Co has been studied with respect to the identification and estimation of degradation products. Detailed information on the radiolysis of succinic acid is important in determining what effect two carboxyl groups in the same molecule would have...
Resource Type:: Dissertation
Full Text:: being carried out. I also wish to express my thanks to the members of Dr. Wang's research

Dynamics of Uranyl Peroxide Nanocapsules

Creator:: Nyman, May and Alam, Todd M.
Abstract:: Discrete aqueous metal oxide polyionic clusters that include aluminum polycations, transition-metal polyoxometalates, and the actinyl peroxide clusters have captivated the interest of scientists in the realm of both their fundamental and applied chemistries. Yet the counterions for these polycations or polyanions are often ignored, even though they are imperative for...
Resource Type:: Article
Full Text:: U28. Journal of the American Chemical Society Article dx.doi.org/10.1021/ja308673f | J. Am. Chem

Effect of oxygen concentration on the structural and magnetic properties of LaRh₁/₂Mn₁/₂O₃ thin films

Creator:: Sheets, W. C., Smith, A. E., Subramanian, M. A., and Prellier, W.
Abstract:: Epitaxial LaRh₁/₂Mn₁/₂O₃ thin films have been grown on (001)-oriented LaAlO₃ and SrTiO₃ substrates using pulsed laser deposition. The optimized thin film samples are semiconducting and ferromagnetic with a Curie temperature close to 100 K, a coercive field of 1200 Oe, and a saturation magnetization of 1.7μB per formula unit. The...
Resource Type:: Article

Zero kinetic energy photoelectron spectroscopy of jet cooled benzo[a]pyrene from resonantly enhanced multiphoton ionization

Creator:: Zhang, Jie, Harthcock, Colin, Han, Fangyuan, and Kong, Wei
Abstract:: We report zero kinetic energy (ZEKE) photoelectron spectroscopy of benzo[a]pyrene (BaP) via resonantly enhanced multiphoton ionization (REMPI). Our analysis concentrates on the vibrational modes of the first excited state (S₁) and those of the ground cationic state (D₀). Similar to pyrene, another peri-condensed polycyclic aromatic hydrocarbon we have investigated, the...
Resource Type:: Article
Full Text:: THE JOURNAL OF CHEMICAL PHYSICS 135, 244306 (2011) Zero kinetic

STEM Graduate Students’ Development at the Intersection of Research, Leadership, and Innovation

Creator:: Lenhart, Cindy, Bouwma-Gearhart, Jana, Keszler, Douglas A., Giordan, Judith, Carter, Rich, and Dolgos, Michelle
Abstract:: Researcher innovation and leadership skills are fundamental to create implementable solutions to pressing societal- and market-based global problems. The Research to Innovation to Society (R2I2S) program is a transformative approach to graduate education, training students at the intersection of research, innovation, and leadership. We detail the design of the program,...
Resource Type:: Preprint
Full Text:: Century: An Agenda for American Science and Technology. National Research Council. (2015). Enhancing the

ScholarsArchive@OSU

Porous metal-organic materials for gas capture

New Graphite Intercalation Chemistry with Alkaline Earth Metals

Synthesis of α-Ketoester- and α-Hydroxyester-Substituted Isoindazoles via the Thermodynamic Coarctate Cyclization of Ester-Terminated Azo-Ene-Yne Systems

Biochemical studies on a plant virus

I. Isolation of certain toxic components of kraft mill waste and attempts to determine their structure. ; II. Studies of the mechanism of the cope rearrangement of 1,2-divinyl-1, 2-cyclohexanediol

Radiolysis of succinic acid in water

Dynamics of Uranyl Peroxide Nanocapsules

Effect of oxygen concentration on the structural and magnetic properties of LaRh₁/₂Mn₁/₂O₃ thin films

Zero kinetic energy photoelectron spectroscopy of jet cooled benzo[a]pyrene from resonantly enhanced multiphoton ionization

STEM Graduate Students’ Development at the Intersection of Research, Leadership, and Innovation

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