Index Catalog // ScholarsArchive@OSU

Preparation and comparative solubility of poly-L-tyrosyl lysozyme and poly-O-methyl-L-tyrosyl lysozyme

Creator:: Venier, Lynn Corrine
Abstract:: In order to examine some possible tyrosyl interactions, poly-tyrosyl lysozyme and poly-O-methyltyrosyl lysozyme were prepared and their solubilities were compared. Both derivatives exhibited similar pH dependent solubilities, showing a minimum solubility at about pH 8. Their solubilities varied with temperature, having a positive enthalpy of solution. The effect of a...
Resource Type:: Masters Thesis
Full Text:: 0.40 7 ó m = m o l e s l i t e r 29 0. 80 0. 60 0. 20 1 Urea Concentration

Preparation and properties of poly-L-tyrosyl acetamidinated ribonuclease

Creator:: Lynn, Jackson
Abstract:: Polypeptidyl derivatives of bovine pancreatic ribonuclease (RNase) containing two or three tyrosine chains with an average of two to three residues per chain have been prepared. The effects of various perturbants such as neutral salts, ethanol, urea and guanidine hydrochloride on the thermal transition of the derivatives have been studied....
Resource Type:: Dissertation
Full Text:: Chemi-strv (Major) Date thesls is presented Mav 12, 1966 Title PREPARATION AI{D PROPERTIES OF POLY-L

Physiological and physical properties of the antithiamine factor in bracken fern (Pteridium aquilinum (L.) Kuhn.)

Creator:: Pierce, Raymond Trussell
Resource Type:: Dissertation
Full Text:: factor in bracken fern (Pteridium aquilinum (L.) Kuhn.) PHYSIOLOGICAL AND PHYSICAL PROPERTIES OF THE

The urea denaturation of bovine serum albumin, polyglycyl bovine serum albumin and poly-L-phenylalanyl bovine serum albumin

Creator:: Chung, Po-luen
Abstract:: A comparative study was made on the effect of urea denaturation of bovine serum albumin (BSA), polyglycyl BSA and poly-L-phenylalanyl BSA. The denaturation process was followed by ultraviolet spectrophotometry and optical rotation. A blue shift in the absorption maximum at 278 mμ was observed in urea denatured proteins, In 7M...
Resource Type:: Masters Thesis
Full Text:: Bovine Serum Albumin and Poly-L-Phenylalanyl Bovine Serum Albumin AN ABSTRACT OF THE THESIS OF PO

A chemical study of the minerals from L-6 chondritic meteorites

Creator:: Curtis, David Ballantyne
Abstract:: Major and minor minerals have been separated from three L-6 chondritic meteorites (Alfianello, Colby (Wisconsin), and Leedey). Olivine, hypersthene, diopside, feldspar, troilite, chromite, phosphate minerals, and metallic minerals were analyzed for major, minor and trace elements using instrumental neutron activation analysis and radiochemical neutron activation analysis techniques. Concentrations df the...
Resource Type:: Dissertation
Full Text:: A chemical investigation of minerals in L-6 chondritic

Siloxy-cope rearrangements of the trans-l-vinylcyclotridec-3-en-l-ol system

Creator:: Bolesta, Richard Edward
Abstract:: The thermolysis of trans-1 -trimethylsiloxy- 1-vinylcyclotridec- 3-ene (VI-OTMS) led to the formation of two major products: 4-vinylcyclotridecanone (VII) and cyclopentadec-5-en-l-one (VIII) after hydrolysis. Ketone VII is produced by a concerted [3, 3] sigmatropic shift, while ketone VIII is formed by a [1, 3] sigmatropic shift with a concerted or diradical...
Resource Type:: Masters Thesis
Full Text:: . T. Wills, A. W. Chin, L. E. Schick and E. S. Walton, ibid. 95, 5281 (1 973). 42 18. R. W. Thies

Investigation of Chain Extension Approaches for the Stereoselective Reagent-Controlled Synthesis of alpha-Heteroatom Substituted Alkyl Boronic Esters

Creator:: Barsamian, Adam L.
Abstract:: Two distinct strategies were explored for the enantioselective synthesis of α-heteroatom substituted alkyl boronic esters by stereoselective reagent-controlled homologation using transient chiral carbenoid reagents CHYMX (Y = heteroatom, X = nucleofuge, M = electrofuge). In the first case, a stereospecific reagent-controlled homologation (sStReCH) approach to α-alkoxyalkylboronates using α-metalated S,O- and...
Resource Type:: Dissertation
Full Text:: AN ABSTRACT OF THE DISSERTATION OF Adam L. Barsamian for the degree of Doctor of Philosophy in

Preparation and characterization of polymer-SiO₂ hybrids

Creator:: Ferguson, Morgan L.
Abstract:: In a search for designed materials that mimic those found in biological systems, combining polymers with inorganic materials in sol-gel chemistry processes has gained momentum in the research world since the 1990's. This work methodically investigated the properties of several related polymer-SiO₂ hybrids prepared by a simple methodology that could...
Resource Type:: Dissertation
Full Text:: Morgan L. Ferguson for the degree of Doctor of Philosophy in Chemistry presented on March 11, 2011

[Lambda hyperon]-((R)-cysteinesulfenamido-N,S) bis (ethylenediamine) cobalt(III) complex : Characterization of the complex and kinetics and mechanism of formation and base-catalyzed decomposition

Creator:: Sanguanruang, Oravan
Resource Type:: Dissertation
Full Text:: [Lambda hyperon]-((R)-cysteinesulfenamido-N,S) bis

Metabolism of L-α-arginine in the biosynthesis of blasticidin S

Creator:: Woo, Nam-tae
Abstract:: Two labelled arginines, DL-[2,3,3,-²H₃]arginine, 8, and DL-[ ¹³C, 2-¹⁵N]arginine, 9, were synthesized. These were fed to cultures of Streptomyces griseochromogenes in order to probe the mechanism of the apparent arginine-2,3- aminomutase reaction occurring in biosynthesis of blasticidin S, 1. In previous studies of the enzymes lysine-2,3- aminomutase and tyrosine-2,3-aminomutase different...
Resource Type:: Masters Thesis
Full Text:: Metabolism of L-α-arginine in the biosynthesis of

ScholarsArchive@OSU

Preparation and comparative solubility of poly-L-tyrosyl lysozyme and poly-O-methyl-L-tyrosyl lysozyme

Preparation and properties of poly-L-tyrosyl acetamidinated ribonuclease

Physiological and physical properties of the antithiamine factor in bracken fern (Pteridium aquilinum (L.) Kuhn.)

The urea denaturation of bovine serum albumin, polyglycyl bovine serum albumin and poly-L-phenylalanyl bovine serum albumin

A chemical study of the minerals from L-6 chondritic meteorites

Siloxy-cope rearrangements of the trans-l-vinylcyclotridec-3-en-l-ol system

Investigation of Chain Extension Approaches for the Stereoselective Reagent-Controlled Synthesis of alpha-Heteroatom Substituted Alkyl Boronic Esters

Preparation and characterization of polymer-SiO₂ hybrids

[Lambda hyperon]-((R)-cysteinesulfenamido-N,S) bis (ethylenediamine) cobalt(III) complex : Characterization of the complex and kinetics and mechanism of formation and base-catalyzed decomposition

Metabolism of L-α-arginine in the biosynthesis of blasticidin S

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