Several experiments were undertaken to investigate the mechanism of
photodechlorination of pentachlorobenzene. The thermal methoxydechlorination
reaction of pentachlorobenzene was studied. In DMSO at 50 °C sodium
methoxide reacts smoothly with pentachlorobenzene to give three
tetrachloroanisole isomers. A second-order kinetic plot for this reaction is linear to
high precision, indicating that...
The carbon is photoelectron spectrum of CO₂ has been measured with very high photon energy resolution. The natural lifetime of the carbon is hole state has been determined from a series of spectra taken at photon energies of 308, 320, and 330 eV. The measured values of the lifetimes show...
Four to six one-gram specimens separated by a distance of
several inches were obtained from each of 23 large chondritic
meteorites (approximately 1 kg each) representing the olivine bronzite
(H5), olivine hypersthene (L6) and enstatite (E5) classifications.
Each specimen was analyzed for Na and Mn via instrumental neutron
activation analysis...
High-precision instrumental neutron activation analysis has
been used to determine Al, Na, Mn, Sc, Cr, Fe, Co, and Ni in a
suite of more than 500 chondrules from 26 distinct meteorites. These
meteorite specimens represent the H, L, LL and C chemical classes
and most of the petrologic types. In...
The relative rates of hydrogen abstraction from a series of 13
arylmethanes by the trichloromethyl radical were determined at 70°.
The attacking radical was generated from bromotrichloromethane us
ing benzoyl peroxide as the initiator. The solvent was benzenebromotrichloromethane.
An excellent correlation, with a coefficient
of 0.977, was obtained when the...
The selective adsorption from a series of binary solutions on an
organoclay complex has been studied in relation to the gelling ability
of this organoclay. Adsorption isotherms were obtained for a series
of polar organic solvents in toluene. The isotherms were of the usual
"S" or "U" type depending upon...