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Using Computational Studies to Characterize Aqueous Metal Clusters : From Spectroscopy to Stability

Creator:: Wills, Lindsay A.
Abstract:: In this dissertation, the spectroscopic properties and thermodynamic stability of a class of materials known as metal oxo and hydroxo clusters are studied. In aqueous solutions, many metals can aggregate into discrete clusters of metals bridged by oxo or hydroxo ligands. These clusters are of particular interest to us for...
Resource Type:: Dissertation
Full Text:: of each isomer was largely determined by how many unfavorable W-W contacts each isomer had, as each

Transpacific transport of benzo[a]pyrene emitted from Asia

Creator:: Zhang, Y., Tao, S., Ma, J., and Simonich, S.
Abstract:: A global-scale three dimensional atmospheric transport and chemistry model was applied to simulate transpacific transport of Benzo[a]pyrene (BaP) emitted from Asia. The model results were compared with observations at six monitoring sites. The annual mean and seasonal variation of transport patterns and the contributions of different Asian source regions to...
Resource Type:: Article

Thermolysis of cis,cis,trans-1-phenyl-1,3,5-heptatriene

Creator:: Tilton, Mary Lehman
Abstract:: Isomerically pure cis,cis,trans-1-pheny1-1,3,5- heptatriene was prepared and cyclized. Ring closure was followed by a 1,5 hydrogen shift, and the only product observed was 1-phenyl -6-methyl -1,3-cyclohexadiene. Rough first order rate constants for thermolysis and the hydrogen shift were determined. Kinetic estimates indicate that the report of disallowed product in a...
Resource Type:: Masters Thesis
Full Text:: . Analysis by gas chromatography (9% SE-30 on Chromsorb W 45/60, 1/4" by 8', 160°, 60 ml/min) showed two

Thermal valence isomerization of trienes

Creator:: Polston, Norman Lee
Resource Type:: Masters Thesis
Full Text:: - pentadiene (XI), and 1 -W- cyclohexeny1)- cis -1, 3- butadiene (X). The trienes IX, X and XI were

Thermal reactions of some selected olefins

Creator:: Moy, Gerald George
Resource Type:: Dissertation

Thermal Cycling Effects on the Thermoelectric Properties of n-Type In,Ce-Based Skutterudite Compounds

Creator:: Biswas, Krishnendu, Subramanian, M. A., Good, Morris S., Roberts, Kamandi C., and Hendricks, Terry J.
Abstract:: n-Type In-filled CoSb₃ is a known skutterudite compound that has shown promising thermoelectric (TE) properties resulting in high dimensionless figure of merit values at elevated temperatures. Use in various waste heat recovery applications will require survival and operation after exposure to harsh thermal cycling environments. This research focused on uncovering...
Resource Type:: Article
Full Text:: thermal cycling runs for this work. The authors also thank Bruce Watson, Pacific North- west National

The thermal decomposition of alkyl benzenediazo sulfones

Creator:: Gabrielsen, Rolf Steven
Resource Type:: Dissertation
Full Text:: since their first reported synthesis by W. Koenigs (46) in 1877. The preparation of the original

The system sulfuryl chloride-sulfur dioxide-chlorine. Equilibrium and catalysis kinetics studies

Creator:: Jischke, John Henry
Abstract:: A spectrophotometric study has been made of catalysis of the decomposition of sulfuryl chloride in carbon tetrachloride solution to an equilibrium mixture of sulfuryl chloride, sulfur dioxide and chlorine. The catalysts were activated charcoal, acetonitrile and 18-crown-6 polyether. A weak acetonitrile-sulfur dioxide complex also was established; formation constants found at...
Resource Type:: Dissertation
Full Text:: 15.74 ml. ,/ to Mercury diffusion pum Stopcock Z Stopcock X to Rough pump Ito M gauge Stop- cock W

The synthesis of an amino alcohol derived from 2,4-quinazolinedione-5-carboxylic acid

Creator:: Wang, Chih Hsing, 1917-
Resource Type:: Dissertation
Full Text:: , çI.I3 clii!)> C::O I' wN Fig.1 w o '"::O I ¿HaBr O H N f vn CH3 CON ii 3 z

The synthesis of amino alcohols derived from pyrimidines

Creator:: Clarke, Ray Allen
Resource Type:: Dissertation
Full Text:: w ïítkro NLNr) CH3 "Off I N N[Ç) -cils CHN2 III N I LLcu3 CH2NR2 Figure I

ScholarsArchive@OSU

Using Computational Studies to Characterize Aqueous Metal Clusters : From Spectroscopy to Stability

Transpacific transport of benzo[a]pyrene emitted from Asia

Thermolysis of cis,cis,trans-1-phenyl-1,3,5-heptatriene

Thermal valence isomerization of trienes

Thermal reactions of some selected olefins

Thermal Cycling Effects on the Thermoelectric Properties of n-Type In,Ce-Based Skutterudite Compounds

The thermal decomposition of alkyl benzenediazo sulfones

The system sulfuryl chloride-sulfur dioxide-chlorine. Equilibrium and catalysis kinetics studies

The synthesis of an amino alcohol derived from 2,4-quinazolinedione-5-carboxylic acid

The synthesis of amino alcohols derived from pyrimidines

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