The effect of quasi-hydrostatic pressure upon the ferromagnetic ground state of magnetodielectric, double-
perovskite La₂ MnNiO₆ is investigated using x-ray absorption spectroscopy and diffraction measurements in a
diamond anvil cell. The Mn-O-Ni superexchange interaction that gives rise to ferromagnetism in this cation-
ordered structure is stable to at least 38...
Understanding structural evolution in solids as composition changes is essential to materials properties prediction. Such structure-properties relationships are the theme of solid state chemistry. Materials scientists and chemists have utilized an abundance of simple crystal structures to enhance understanding of chemical and structural origins of properties in materials for decades....
This dissertation presents a study of structure-property relationships within 3d/4d metal oxides containing precious metals through detailed structure refinements using high-resolution neutron and X-ray diffraction data along with exploration of the resultant properties.
Oxides of 4d or 5d transition metals tend to show new topological phases due to significant spin-orbit...
Solid state inorganic oxides play an important role in next generation electronics based on their stability, versatility, and enhanced properties over other materials. However, in order to design or tune these materials for a desired functionality it is necessary to fully understand the structure behind the properties exhibited. This dissertation...
The abundance of copper was determined in four to six one-gram
specimens separated by a distance of several inches from each
of 23 large chondritic fragments (greater than 1 kg) via instrumental
neutron activation analysis and counting of the annihilation N-rays of
⁶⁴Cu. It is believed that an accuracy of...
Due to the high cost of precursor materials, complex oxides of 4d and 5d transition metals are under-studied compared to their 3d counterparts. Recent studies have shown that oxides containing heavier transition metals can exhibit exotic electronic states due to presence of strong spin-orbit coupling. The goal of this dissertation...
Four to six one-gram specimens separated by a distance of
several inches were obtained from each of 23 large chondritic
meteorites (approximately 1 kg each) representing the olivine bronzite
(H5), olivine hypersthene (L6) and enstatite (E5) classifications.
Each specimen was analyzed for Na and Mn via instrumental neutron
activation analysis...