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Filtering by: Creator Kaufman, Diane Academic Affiliation Chemistry

A multivariate statistical approach to identifying organic compounds using an oscillating plasma glow discharge detector for gas chromatography

Creator:

Smith, Diane Lynn

Abstract:

An oscillating plasma glow discharge detector for gas chromatography is used to obtain fingerprint information about an analyte by combining both the average cell current and oscillation frequency signals. Five homologs each of the n-alkanes, 1-alkenes, 1-alkynes, 2-ketones and aldehydes are studied. Although triplicate determinations had some scatter due to...

Resource Type:

Dissertation

Full Text:

THESIS OF Diane Lynn Smith for the degree of Doctor of Philosophy in Chemistry presented on Apr, 1. 4
Formation of alkyl-and dialkylcarbenes. The 3-cyclohexenyl carbinyl carbene system

Creator:

Crouse, Dale McClish

Abstract:

The 3-cyclohexenyl carbinyl carbene species was formed by the thermal decomposition of the p-toluenesulfonylhydrazone sodium salt and by oxidation of the hydrazone. Several oxidizing agents were studied. The products were investigated under aprotic and protic conditions and at various temperatures. The diazocompound was formed as an intermediate and found to...

Resource Type:

Masters Thesis
Steroid dialkylcarbene reactions

Creator:

Dixon, Dale David

Abstract:

Steroid carbenes have been investigated as synthetic intermediates. Basic decomposition of 4-en-3-one tosylhydrazones (and other A-ring systems) gives varying amounts of 2, 4-dienes, and solvent derived products with diglyme, heptane, tetrachloroethylene, carbon tetrachloride, benzene and cyclohexene. A method for separating complex product mixtures was developed and a study of the...

Resource Type:

Dissertation