Index Catalog // ScholarsArchive@OSU

Using Metal-Oxo Clusters to Expand Actinide Chemistry

Creator:: Colliard, Ian
Abstract:: A molecular approach to metal oxides allows to the study to fundamental bonding and formation behavior for such metals. Moreover, the molecular nature of such oxides or metal-oxo clusters allows the possibility of exploitation of the properties of the parent oxides. The tetravalent metals, in specific, (M=Zr, Hf, Ce, Th,...
Resource Type:: Dissertation
Full Text:: Ian Colliard for the degree of Doctor of Philosophy in Chemistry presented on February 28, 2022

Evidence for a soluble high energy intermediate of oxidative phosphorylation in mitochondria from blowflies

Creator:: Sun, Albert Yung-Kwang
Resource Type:: Dissertation
Full Text:: gratitùde to Dr. LeMar F. Remmert for his kindness and continuous guidance, and also to Dr. Ian J

Size-Dependent Structural Distortions in One-Dimensional Nanostructures

Creator:: Anderson, Michael D., Heideman, Colby L., Lin, Qiyin, Smeller, Mary, Kokenyesi, Robert, Herzing, Andrew A., Anderson, Ian M., Keszler, Douglas A., Zschack, Paul, and Johnson, David C.
Abstract:: No abstract.
Resource Type:: Article
Full Text:: . Heideman, Qiyin Lin, Mary Smeller, Robert Kokenyesi, Andrew A. Herzing, Ian M. Anderson, Douglas A. Keszler

High-resolution infrared studies of the ν10, ν11, ν14, and ν18 levels of [1.1.1]propellane

Creator:: Kirkpatrick, Robynne, Masiello, Tony, Martin, Matthew, Nibler, Joseph W., Maki, Arthur, Weber, Alfons, and Blake, Thomas A.
Abstract:: This paper is a continuation of earlier work in which the high resolution infrared spectrum of [1.1.1]propellane was measured and its k and l structure resolved for the first time. Here we present results from an analysis of more than 16,000 transitions involving three fundamental bands v₁₀ (E' - A'₁),...
Resource Type:: Article
Full Text:: a given vibrational state v is given by Ev ¼ Gðv ; lÞ þ FvðJ;K; lÞ; ð1Þ where Gðv ; lÞ is the

Coriolis analysis of several high-resolution infrared bands of bicyclo[111]pentane-d₀ and -d₁

Creator:: Perry, A., Martin, M. A., Nibler, J. W., Maki, A., Weber, A., and Blake, T. A.
Abstract:: High-resolution infrared absorption spectra have been analyzed for two bicyclo[111]pentane isotopologues, C₅H₈ (-d₀) and C₅H₇D (-d₁), where in the latter the D-atom replaces a hydrogen on the C₃ symmetry axis such that the molecular symmetry is reduced from D₃ₕ to C₃ᵥ. Two (a"₂) parallel bands, v₁₇ and v₁₈, of bicyclopentane-d₀...
Resource Type:: Article
Full Text:: energy of a given vibrational state v is given by Ev ¼ Gðv ; lÞ þ FvðJ;K; lÞ; ð1Þ where G(v, l) is the

High resolution spectroscopy of sulfur trioxide and carbon suboxide

Creator:: Masiello, Tony
Abstract:: High resolution spectroscopy was used to study the properties of two simple polyatomic molecules, sulfur trioxide, SO₃, and carbon suboxide, C₃O₂. The fundamental modes and several hot bands of the ¹⁸O isotopic fonns of SO₃ (³²S¹⁸O₃ and ³⁴S¹⁸O₃) have been investigated using both infrared spectroscopy and coherent anti-Stokes Raman scattering...
Resource Type:: Dissertation
Full Text:: vibrational state designation is given by the quantum level (v1 v2 v v), so, for example, the ground state

Analytical and mechanistic studies of the chemiluminescence oxidation of hydroxy-containing compounds

Creator:: Vasquez de Montalvo, Socorro I.
Abstract:: This thesis is concerned with the development and use of routine analysis techniques based on chemiluminescence (CL) detection for: 1) ethanol in gin down to the 0.3% (v/v) level; 2) the antioxidants propyl gallate and BHA in lard to levels as low as 0.3 and 0.2 mg/L, respectively; 3) pyrogallol...
Resource Type:: Dissertation
Full Text:: the 0.3% (v/v) level; 2) the antioxidants propyl gallate and BHA in lard to levels as low as 0.3 and

Purification and characterization of a cytoplasmic apyrase plumules of Pisum sativum

Creator:: Nishikawa, Alfred Hirotoshi
Abstract:: The 105,000 x g supernatant fluid (S[subscript HS]) from extracts of pea seedlings (Pisum sativum, var. Alaska) etiolated for 60 hours yielded a very potent adenosine triphosphatase activity. This activity was designated as an apyrase when the reaction stoichiometry indicated that adenosine triphosphate (ATP) was hydrolyzed to adenosine monophosphate (AMP)...
Resource Type:: Dissertation
Full Text:: expressed to Drs. LeMar F. Remmert, Anne Deeney, and Ian J. Tinsley for their helpful suggestions and

Uranyl Peroxide Cluster Formation Pathway and the Role of the Alkali Counterion

Creator:: Arteaga, Ana
Abstract:: Uranyl peroxide clusters are the newest family of polyoxometalates, discovered in 2015. Although this family is new, over 70 topologies have been reported. However, we lack the fundamental understanding of assembly mechanisms, particularly the role of the alkali countercations. Here, we use a wide range of solution and solid-state characterization...
Resource Type:: Dissertation
Full Text:: importantly, we have found that in the presence of Cs+ peroxide reduces uranium from U(VI) (Cs-U1) to U(V

Polyoxoniobates: fundamental solubility trend and their application in solution and on the surface of thin films

Creator:: Rahman, Tasnim
Abstract:: Polyoxometalates (POMs) are anions consisting of three or more early transition metals ™ (Gr V and VI) oxoanions (in their highest oxidation state) linked together by a shared oxygen bond to form a 3D framework. Polyoxometalates (POMs) are a rapidly growing class of metal oxo clusters with a wide range...
Resource Type:: Dissertation
Full Text:: or more early transition metals ™ (Gr V and VI) oxoanions (in their highest oxidation state) linked

ScholarsArchive@OSU

Using Metal-Oxo Clusters to Expand Actinide Chemistry

Evidence for a soluble high energy intermediate of oxidative phosphorylation in mitochondria from blowflies

Size-Dependent Structural Distortions in One-Dimensional Nanostructures

High-resolution infrared studies of the ν10, ν11, ν14, and ν18 levels of [1.1.1]propellane

Coriolis analysis of several high-resolution infrared bands of bicyclo[111]pentane-d₀ and -d₁

High resolution spectroscopy of sulfur trioxide and carbon suboxide

Analytical and mechanistic studies of the chemiluminescence oxidation of hydroxy-containing compounds

Purification and characterization of a cytoplasmic apyrase plumules of Pisum sativum

Uranyl Peroxide Cluster Formation Pathway and the Role of the Alkali Counterion

Polyoxoniobates: fundamental solubility trend and their application in solution and on the surface of thin films

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