Index Catalog // ScholarsArchive@OSU

Synthesis of substituted cyclooctatetraenide dianions ; Cycloheptadienyl complexes of the ḏ- and f̲-transistion elements ; Reactions of cyclohexanone with metal vapors

Creator:: Miller, Jeffrey Templeton
Abstract:: I. Lithium alkyl and aryl monosubstituted cyclooctatetraenide dianions (Li₂ C₈H₇-R; R = methyl, n- butyl, sec- butyl, tert- butyl, phenyl and benzyl) were synthesized by the reaction of the appropriate organolithium reagent with cyclooctatetraene in diethyl ether or tetrahydrofuran. The reaction occurred cleanly and with good yield of lithium monosubstituted...
Resource Type:: Dissertation
Full Text:: D UC1 4 02, Ram ethyl 11=n- butyl R=sec - butyl R=t-butyl R =phenyl R=benzyl Figure 1-1

Hydrogen abstraction from substituted t-butylbenzenes

Creator:: Harvey, Robert Louis
Abstract:: A study of the relative rates of the alkyl hydrogen abstraction from a series of meta and para substituted t-butylbenzenes by the chlorine atom at 70°C has been carried out. Application of the Hammett equation yielded a ρ value of -0.44 for the para compounds. Possible explanations for the non-linearity...
Resource Type:: Masters Thesis
Full Text:: 0.025d p- Phenoxy- t- butylbenzene 5 1,22 ± 0.030 m- Phenoxy- t- butylbenz ene 8 2. 50 ± 0.387 d

Characterization and applications of polyphenol chemiluminescence reactions and flow cell instrumentation

Creator:: Miller, Robert J. (Robert James), 1933-
Resource Type:: Dissertation
Full Text:: chemiluminescence reactions and flow cell instrumentation AN ABSTRACT OF THE THESIS OF Robert James Miller for

Preparation and characterization of n-octadecylcycloazadiboron

Creator:: Heusser, Roger Karvel
Abstract:: A preparative method for a new compound n-octadecylcycloazadi-boron (CAB), in high yield has been developed. CAB was isolated as an intermediate in the octadecylamine-catalyzed hydrolysis of pentaborane. The most probable structure of CAB can be regarded as a derivative of the three membered ring cycloazadiboron with a n-octadecyl group substituted...
Resource Type:: Masters Thesis
Full Text:: gratitude to Dr. T. D. Parsons for the direction and inspiration bestowed during the pursuit of this work

Low temperature thermal analysis of some boron halide complexes with weak Lewis bases

Creator:: Lerch, Ronald Edwin
Abstract:: Thermal analysis was used to investigate the following seven systems: H₂S-B₂F₄, SOF₂-B₂F₄, COC1₂-B₂F₄, SF₄-B₂F₄, Xe-BF₃, NF₃-BF₃, and NF₃-BC1₃. In two of the seven systems compound formation was observed. In the system, H₂S-B₂F₄ the compounds H₂S[superscript .]B₂F₄ and 2H₂S[superscript .]B₂F₄ are formed. The compound H₂S[superscript .]B₂F₄ has a melting point of...
Resource Type:: Dissertation
Full Text:: ACKNOWLEDGEMENT The author wishes to express his appreciation to Dr. T. D. Parsons for his guidance

The chemistry of perillaldehyde and certain of its derivatives

Creator:: Miller, Kenneth L.
Resource Type:: Dissertation
Full Text:: in on this co t . • The t1 t-ct-oey add.1t1on ot d r obt ln h v • t t co n th

Optimization by transfer function estimation of the galvanovoltammetric determination of dissolved chlorine in a flowing stream

Creator:: Miller, Clinton Earl
Abstract:: Optimization of the galvanovoltammetric determination of dissolved chlorine in a flowing stream was achieved through the use of an analog computational device and improvements in the design of the galvanovoltammetric cell and accompanying electronic circuitry. An analysis system, applicable to industrial use over a range of flow rates and dissolved...
Resource Type:: Masters Thesis
Full Text:: EARL MILLER for the MASTER OF SCIENCE (Name) (Degree) in Chemistry (Analytical) presented on March 31

The rotational motion of molecules in crystalline solids

Creator:: Miller, R. E.
Abstract:: Theoretical studies and experimental results are presented for the rotational motion of molecule's in crystalline solids. The group theory is solved for molecules of any symmetry matrix isolated at a site in a crystal field of any symmetry. As the potential terrier to rotation of the molecule relative to the...
Resource Type:: Dissertation
Full Text:: ,,. OOOOOO00000.71 2, A T Molecule in a T d Field-d 78 3. A Td Molecule in a D2d Field OO OOOO .0.0.00000 0083 E

Synthesis and oxidation of cysteine- and penicillamine- containing Fe(III) and Co(III) complexes. Analogs for the active metal sites of the cysteine and cysteamine dioxygenases

Creator:: Miller, Krys J.
Abstract:: The first part of this thesis describes a study of the characteristics of oxidation of a 1:2 iron(III):thiolate system in methanolic solution and in water. This system was investigated as a potential analog for the cysteine- and cysteamine-dioxygenase catalyzed 0₂-oxidation of cysteine and cysteamine, respectively, to the corresponding sulfinic acids....
Resource Type:: Dissertation
Full Text:: dioxygenases AN ABSTRACT OF THE THESIS OF KRYS Y. MILLER for the degree of DOCTOR OF PHILOSOPHY in

Acidity and basicity measurements of some silicone gas chromatographic liquid stationary phases

Creator:: Miller, Gary J.
Resource Type:: Masters Thesis
Full Text:: chromatographic liquid stationary phases AN ABSTRACT OF THE THESIS OF GARY J. MILLER for the degree of MASTER

ScholarsArchive@OSU

Synthesis of substituted cyclooctatetraenide dianions ; Cycloheptadienyl complexes of the ḏ- and f̲-transistion elements ; Reactions of cyclohexanone with metal vapors

Hydrogen abstraction from substituted t-butylbenzenes

Characterization and applications of polyphenol chemiluminescence reactions and flow cell instrumentation

Preparation and characterization of n-octadecylcycloazadiboron

Low temperature thermal analysis of some boron halide complexes with weak Lewis bases

The chemistry of perillaldehyde and certain of its derivatives

Optimization by transfer function estimation of the galvanovoltammetric determination of dissolved chlorine in a flowing stream

The rotational motion of molecules in crystalline solids

Synthesis and oxidation of cysteine- and penicillamine- containing Fe(III) and Co(III) complexes. Analogs for the active metal sites of the cysteine and cysteamine dioxygenases

Acidity and basicity measurements of some silicone gas chromatographic liquid stationary phases

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