Index Catalog // ScholarsArchive@OSU

Total Synthesis of Goniomitine : Development of Aminal and α-Amino Radicals in the Synthesis of Nitrogen-Rich Natural Products

Creator:: Vellucci, Jessica K.
Abstract:: Aminal radical intermediates were generated by the method of radical translocation and reacted in C-C bond forming reactions with electronically deficient alkenes (Schiedler et al. Org. Lett. 2012, 14, 6092). Aminal radical intermediates can participate in inter- and intra-molecular reactions using both Bu3SnH and (TMS)₃SiH as hydride donors. Carbon–carbon bonds...
Resource Type:: Dissertation
Full Text:: THE DISSERTATION OF Jessica K. Vellucci for the degree of Doctor of Philosophy in Chemistry

Storage Battery Chemistries with Earth Abundant Charge Carriers

Creator:: Hong, Jessica Junghwa
Abstract:: The demand for the development of sustainable energy is an all time high as we burn through limited fossil fuel reserves and as environmental concerns rise every year. Renewable energy sources such as wind and solar power have limitations due to inconsistent power supply that cannot meet the regular needs...
Resource Type:: Dissertation
Full Text:: ) Figure Page 3.2 GCD profiles for different concentrations (10, 15,20 m) of ZnCl2 with 5 m KI electrolyte

Thermodynamics of the reaction between F and M centers

Creator:: Zahrt, John David
Resource Type:: Masters Thesis
Full Text:: LIST OF FIGURES Figure Page 1 R and M Centers after Seitz 7 2 Knox model derived from resonance

Thermodynamics of the reaction between F and M centers in KBr

Creator:: Li, Tsai-chi
Resource Type:: Masters Thesis
Full Text:: CONTENTS Page INTRODUCTION 1 General Properties 1 F Centers 1 Secondary Centers 3 M Center 6

Mass spectrometric analysis of bovine neurofilament proteins NF-L, NF-M, and NF-H : peptide mapping, phosphorylation and alkylation site identification

Creator:: Mixon, April E.
Abstract:: Neurofilament proteins are intermediate filaments found in the neuronal cytoskeleton. Phosphorylation of these proteins is considered important for the assembly and stability of the filaments. Accurate molecular weights have been difficult to measure, largely because the high degree of phosphorylation results in M[subscript r]'S that are significantly greater than dictated...
Resource Type:: Masters Thesis
Full Text:: Bovine Neurofilament Proteins NF-L. NF-M, and NF-H: Peptide Mapping, Phosphorylation and Alkylation

The development of aminal radicals for the synthesis of nitrogen-rich natural products

Creator:: Schiedler, David A.
Abstract:: Organic compounds which contain one or more nitrogen atoms are especially important as they are disproportionately represented among biologically active molecules. As a result, significant effort has been focused on the development of methods for the synthesis of nitrogenous molecules. We identified the aminal as an under-explored functional group. Despite...
Resource Type:: Dissertation
Full Text:: Using Aminal Radicals David A. Schiedler, Jessica K. Vellucci, and Christopher M. Beaudry

Displacement-based fluorescent microRNA biosensors : design principles and analytical metrics

Creator:: Larkey, Nicholas E.
Abstract:: One post-transcriptional mechanism that regulates the progression of cancer and other diseases involves small 22-23 nucleotide sequences called microRNA (miR). Early detection of small changes in concentration of these biomarkers holds potential to diagnose diseases at their earliest stages. Use of current nucleic-acid based biosensors, like molecular beacons, for in...
Resource Type:: Dissertation
Full Text:: Abstract approved: ______________________________________________________ Sean M. Burrows

A Pyrone Diels–Alder Approach to Substituted Indoles and Carbazoles and the Synthesis of New Ropinirole Analogues

Creator:: Points, Gary L., III
Abstract:: Aromatic heterocycles are core structural motifs in natural products, pharmaceuticals and biological polymers. Indoles, in particular, represent a significant subclass of aromatic heterocycles, both in terms of sheer numbers, but also in biological and pharmaceutical relevance. As such, new methodologies for the synthesis of indoles represent an important and continually...
Resource Type:: Dissertation
Full Text:: Christopher M. Beaudry Aromatic heterocycles are core structural motifs in natural products

Synthesis of α-Ketoester- and α-Hydroxyester-Substituted Isoindazoles via the Thermodynamic Coarctate Cyclization of Ester-Terminated Azo-Ene-Yne Systems

Creator:: McClintock, Sean P., Forster, Nathan, Herges, Rainer, and Haley, Michael M.
Abstract:: The synthesis of isoindazoles bearing α-ketoester and α-hydroxyester groups via the coarctate cyclization of ester terminated azo-ene-yne precursors is described. Whereas previous studies on isoindazole formation have shown the reaction to proceed through a kinetic coarctate pathway, functionalization of the terminal acetylene with a methyl ester sufficiently stabilizes the carbene...
Resource Type:: Article
Full Text:: ‡ and Michael M. Haley†* Department of Chemistry, University of Oregon, Eugene, Oregon 97403-1253

Inclusively Recognizing Faculty Innovation and Entrepreneurship Impact Within Promotion and Tenure Considerations

Creator:: Bouwma-Gearhart, Jana, Lenhart, Cindy, Carter, Rich, Mundorff, Karl, Cho, Holly, and Knoch, Jessica
Abstract:: Faculty research has led to a plethora of innovations and entrepreneurial resources (I&E), allowing for enhancements to the greater social good including, but not limited to, technological and economic advancements. Faculty I&E also enhances faculty competitiveness for funding, institutional image and fundraising, and supports students’ workforce preparation. Over time institutions...
Resource Type:: Preprint
Full Text:: Carter2, Karl Mundorff3, Holly Cho4, & Jessica Knoch1 1College of Education, Oregon State

ScholarsArchive@OSU

Total Synthesis of Goniomitine : Development of Aminal and α-Amino Radicals in the Synthesis of Nitrogen-Rich Natural Products

Storage Battery Chemistries with Earth Abundant Charge Carriers

Thermodynamics of the reaction between F and M centers

Thermodynamics of the reaction between F and M centers in KBr

Mass spectrometric analysis of bovine neurofilament proteins NF-L, NF-M, and NF-H : peptide mapping, phosphorylation and alkylation site identification

The development of aminal radicals for the synthesis of nitrogen-rich natural products

Displacement-based fluorescent microRNA biosensors : design principles and analytical metrics

A Pyrone Diels–Alder Approach to Substituted Indoles and Carbazoles and the Synthesis of New Ropinirole Analogues

Synthesis of α-Ketoester- and α-Hydroxyester-Substituted Isoindazoles via the Thermodynamic Coarctate Cyclization of Ester-Terminated Azo-Ene-Yne Systems

Inclusively Recognizing Faculty Innovation and Entrepreneurship Impact Within Promotion and Tenure Considerations

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