A continuous amperometric monitor for aqueous sulfite solutions
has been developed employing the electro-oxidation of sulfur (IV)
in 0. 1 M sulfuric acid at a glassy carbon test electrode. The monitor
employs a hydrodynamic flow cell, in which the solution stream
enters the cell through an orifice impinging on the...
Reaction of 4, 6-dimethoxy-5-nitropyrimidine [I], with refluxing
pyridine, was discovered to yield the methylpyridinium salt of
1, 6-dihydr -4-hydroxy-1-methyl-5-nitro-6-oxopyrimidine [III]. Possible
use of I as a general N-methylating agent was explored. No
appreciable reaction occurred between I and refluxing excess n-butyl
alcohol. Similar reaction involving quinoline failed to yield an...
A synthetic approach toward the two major fragments of cathedulin K-19,
euonyminol (4) and dimethyl cathate (69), was investigated. Synthesis of
dimethyl cathate was accomplished in 3 steps starting from 73. Efforts directed
towards the synthesis of euonyminol, a highly oxygenated dihydroagarofuran
sesquiterpene, was advanced to a stage in which...
Solubility studies on the heavy metal sulfides in liquid hydrogen
sulfide at room temperature were carried out using the isopiestic
method. The results were compared with earlier work and with a
theoretical result based on Raoult's Law. A relative order for the
solubilities of sulfur and the sulfides of tin,...
The infrared spectra of the metaborate monomer and trimer
ions in NaC1, KC1, and KBr were studied. These spectra contain
bands due to the trimer in solid solution, in a second phase of the appropriate
potassium or sodium salt, and perhaps on adjacent lattice
sites. Furthermore, complex equilibria exist between...
The transport and deposition of airborne contaminants, including semivolatile
organic compounds (SOCs), to high elevation ecosystems is
recognized as a potential threat to these ecosystems. The objectives of
this research were to develop an analytical method to measure a wide
range of SOCs in high elevation lake sediment and to...